Tetrahedron p. 13727 - 13738 (1997)
Update date:2022-08-05
Topics:
Lusinchi, Xavier
Hanquet, Gilles
Oxaziridinium 5 efficiently epoxidises olefins. It reacts as an electrophilic reagent and does not transfer its oxygen to deactivated double-bonds or carbonyl functions. Epoxidation of cyclic allylic acetates shows a remarkable diastereoselectivity leading to the syn isomer. We propose that the epoxidation reaction proceeds through a one-step process.
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