Oxidative Desulfurization-Fluorination of 1-Substituted 2,2,2-Tris(methylthio)ethanol Induces Difluorination under Oxidation or Rearrangement

DOI: 10.1016/0040-4039(95)01234-9

Source and publish data:

Tetrahedron Letters p. 6121 - 6122 (1995)

Update date:2022-08-02

Topics:

Authors:

Kuroboshi, Manabu

Furuta, Satoru

Hiyama, Tamejiro

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Article abstract of DOI:10.1016/0040-4039(95)01234-9

Oxidative desulfurization-fluorination of RCH(OH)C(SMe)3 using n-Bu4NH2F3 and 1,3-dibromo-5,5-dimethylhydantoin gave RC(O)CF2SMe, whereas treatment of the same substrates with Et2NSF3 afforded RCH(SMe)CF2SMe.

Full text of DOI:10.1016/0040-4039(95)01234-9

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