Oxidative Desulfurization-Fluorination of 1-Substituted 2,2,2-Tris(methylthio)ethanol Induces Difluorination under Oxidation or Rearrangement

DOI: 10.1016/0040-4039(95)01234-9

Source and publish data:

Tetrahedron Letters p. 6121 - 6122 (1995)

Update date:2022-08-02

Topics:

Authors:

Kuroboshi, Manabu

Furuta, Satoru

Hiyama, Tamejiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)01234-9

Oxidative desulfurization-fluorination of RCH(OH)C(SMe)3 using n-Bu4NH2F3 and 1,3-dibromo-5,5-dimethylhydantoin gave RC(O)CF2SMe, whereas treatment of the same substrates with Et2NSF3 afforded RCH(SMe)CF2SMe.

Full text of DOI:10.1016/0040-4039(95)01234-9

Products guided by the article

Product name:1,1,1-tris(methylthio)-4-phenyl-2-butanol

Cas No:170654-29-2

R&D Labs maybe for 170654-29-2

Shanghai Science Peptide Biological Technology Co.,ltd

website:http://www.scipeptide.com

Contact:+86-21-51099675

Address:No.8 Changyang Rd
Yurui(Shanghai)Chemical Co.,Ltd

Contact:0086 21-50456736

Address:No.3188 Xiupu Road,Shanghai
Hubei Lingsheng Pharmaceuticals Co., Ltd.

Contact:+86-0710-3538058

Address:Xiangyang City Xiangcheng Economic Development Zone, Hubei Province
GM CHMICAL CO., LTD

Contact:0086-21-80264647

Address:RM 202, NO 1602 West Zhongshan Rd, Shanghai, China
Simagchem Corporation

website:http://www.simagchem.com

Contact:+86-592-2680277

Address:21/F Hualong Office Building,No.6 Hubin East Road, Xiamen,China

Relevant to this article

Asymmetric protected enoates as key intermediates towards an EPC synthesis of (+)-heptelidic acid

Doi:10.1016/0040-4039(95)01538-S
(1995)
An enantioselective synthesis of (11R,12S,13S,9Z,15Z)-9,12,13-trihydroxyoctadeca-9,15-dienoic acid, a self-defensive substance against rice blast disease

Doi:10.1246/cl.1995.763
(1995)
Synthesis, bioactivation and anti-HIV activity of 4-acyloxybenzyl bis(nucleosid-5'-yl) phosphates

Doi:10.1080/15257779508009491
(1995)
Synthesis of chiral N-alkyl-cyclopentadienyl sulfonamides

Doi:10.1016/0957-4166(95)00264-P
(1995)
Doi:10.1039/j39670001762
(1967)
Design and study of synthetic chiral nanoscopic assemblies. Preparation and characterization of optically active hybrid, iodonium - Transition-metal and all-transition-metal macrocyclic molecular squares

Doi:10.1021/ja961444r
(1996)

Article Doi