Tetrahedron Letters p. 879 - 882 (1997)
Update date:2022-08-03
Topics:
Masnyk, Marek
α-Iodoalkyl phenyl sulfones undergo radical rearrangement to 5-iodo-1-phenylsulfanyl derivatives when heated with benzoyl peroxide or when irradiated with a sunlamp in the presence of hexabutylditin. Products of these rearrangements, upon treatment with bases, can be easily and stereoselectively converted into trans phenylsulfonyl derivatives of cyclopentane.
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