Synthesis and investigation of mono- and binuclear cyano-bridged complexes of rhodium, ruthenium, and palladium

DOI: 10.1007/BF00696933

Source and publish data:

Russian Chemical Bulletin p. 941 - 945 (1995)

Update date:2022-08-03

Topics:

Authors:

Bezrukova, A. A.

Khandakarova, V. S.

Petrovskii, P. V.

Rubezhov, A. Z.

Vygodskii, Ya. S.

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1007/BF00696933

Binuclear Rh^III and Ru^II complexes of the 1-CNM²>⁺BF4^- (M¹ and/or M² are (η⁵-Cp)(η³-C3H5)Rh and (η⁶-C6H6)(η³-C3H5)Ru) type, heteronuclear organometallic compound (η⁵-Cp)(η³-C3H5)RhCNPd(η³-C3H5)Cl, and mononuclear Rh^III and Ru^II complexes <(η³-C3H5)LM(MeCN)>⁺BF4^- (M = Rh, L = η⁵-Cp; M = Ru, L = η⁶-C6H6) were synthesized.An electrochemical study of these compounds in solutions demonstrates that the bond between the bridged CN ligand and the metal atoms is rather strong, and there is no dissociation into mononuclear fragments in solutions.The kinetics of the reaction of <(η⁵-Cp)(η³-C3H5)Rh(MeCN)>⁺BF4^- with halide ions was studied by electrochemical methods.The ligand exchange proceeds by a bimolecular dissociative-exchange mechanism.

Full text of DOI:10.1007/BF00696933

Products guided by the article

Product name:[η(6)-benzene-η(3)-allyl(acetonitrile)ruthenium] tetraphenylborate

Cas No:171977-50-7

R&D Labs maybe for 171977-50-7

Taimai Sanluck Pharmaceutical Co.,Ltd

Contact:86-592-7662921

Address:8D,No.186,Huarong Road,Huli,Xiamen,China
ANHUI CHEM-BRIGHT BIOENGINEERING CO.,LTD

Contact:86-561-4080321

Address:No.8 Lieshan Industrial Zone of Huaibei
Jinan Great Chemical Co.,Ltd.

Contact:+86-531-58668191 58668193 58668196 58661173

Address:No 55,Beixiaoxinzhuang West Street,Jinan City, Shandong Province
Hangzhou Yingshanhua Pigment Chemicals Co.,Ltd.

Contact:+86-0150-58101658

Address:Nanyang Economic DevelopmentZong,Xiaoshan,Hangzhou,China
Taiwan Surfactant Corp.

Contact:886 2 2541 0022

Address:8 Fl., No. 11, Sec. 1, Chung Shan North Rd., Taipei, Taiwan R.O.C.

Relevant to this article

N-methyl-D-aspartic acid receptor agonists: Resolution, absolute stereochemistry, and pharmacology of the enantiomers of 2-amino-2-(3-hydroxy-5-methyl-4-isoxazolyl)acetic acid

Doi:10.1021/jm950393q
(1996)
Staudinger/aza-Wittig reaction to access N^β-protected amino alkyl isothiocyanates

Doi:10.1039/c8ob01061g
(2018)
Calix[4]indoles: New macrocyclic tetra(indolylmethylene) compounds with 2,7-linkages

Doi:10.1016/0040-4039(95)01516-K
(1995)
Facile synthesis of c/s-2-alkyl-3-trialkylsilyloxycycloalkanones via the non-aldol aldol rearrangement of 2,3-epoxycycloalkanols

Doi:10.1021/ol800423m
(2008)
Polycarbon ligands: Synthesis and characterization of the phosphinodiynes Ph₂PC≡C-C≡CR (R = Bu^t, Ph, SiMe₃),the μ-η¹,η²_{α, β}-butadiynyl complexes Ru₂(CO)₆-(μ-PPh ₂

Doi:10.1139/v96-262
(1996)
Uranium-sulfilimine chemistry. Hydrolysis of Cp*₂UCl₂ with HNSPh₂·H₂O and the crystal structure of Cp*₂UCl(OH)(HNSPh₂), a metallocene terminal hydroxy complex of tetravalent uranium

Doi:10.1016/j.jorganchem.2004.03.029
(2004)

Article Doi