Synthesis of Carboxylated Pyrrolidine Derivatives via 1,3-Dipolar Cycloadditions of Homochiral Double-Stabilised E-Azomethine Ylids.

DOI: 10.1016/0957-4166(95)00198-X

Source and publish data:

Tetrahedron Asymmetry p. 1557 - 1560 (1995)

Update date:2022-08-03

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Authors:

Harwood, L. M.

Lilley, I. A.

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Article abstract of DOI:10.1016/0957-4166(95)00198-X

The preparation and subsequent diastereoselective 1,3- dipolar cycloaddition of E-carboethoxy-substituted azomethine ylids derived by condensating 5-(S)-phenylmorpholinone (1) with ethyl glyoxalate is described.Removal of the chiral template furnishes enantiomerically pure pyrrolidine-2,5-dicarboxylate derivatives.

Full text of DOI:10.1016/0957-4166(95)00198-X

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