Journal of the Chemical Society. Chemical communications p. 2001 - 2002 (1995)
Update date:2022-08-04
Topics:
Nagumo, Shinji
Irie, Shigeyuki
Akita, Hiroyuki
Excess BF3 causes regioselectivity reversion in the reaction of methyl 4,5-epoxypent-2-enoate 1 with Ph2CuLi; this is rationalised by a two step conversion via methyl 4-bromo-5-hydroxypent-2-enoate 5.
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