Reactions of C-H bonds in organic oxygenates with octaethylporphyrinato rhodium(II) and iridium(II) dimers

DOI: 10.1016/0022-328X(95)05569-B

Source and publish data:

Journal of Organometallic Chemistry p. 47 - 56 (1995)

Update date:2022-08-05

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Authors:

Rossi, Kenneth J. Del

Zhang, Xiao-Xiang

Wayland, Brandford B.

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Article abstract of DOI:10.1016/0022-328X(95)05569-B

Metalloporphyrin dimers, <(OEP)M>2 (1a, M - Rh; 1b, M = Ir; OEP = octaethylporphyrin dianion), are observed to react with C-H bond units in aldehydes, ketones and benzyl alcohols.Aldehydes, R2CHCHO, preferentially react at the alkyl group adjacent to the

Full text of DOI:10.1016/0022-328X(95)05569-B

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