Reactions of C-H bonds in organic oxygenates with octaethylporphyrinato rhodium(II) and iridium(II) dimers

DOI: 10.1016/0022-328X(95)05569-B

Source and publish data:

Journal of Organometallic Chemistry p. 47 - 56 (1995)

Update date:2022-08-05

Topics:

Authors:

Rossi, Kenneth J. Del

Zhang, Xiao-Xiang

Wayland, Brandford B.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(95)05569-B

Metalloporphyrin dimers, <(OEP)M>2 (1a, M - Rh; 1b, M = Ir; OEP = octaethylporphyrin dianion), are observed to react with C-H bond units in aldehydes, ketones and benzyl alcohols.Aldehydes, R2CHCHO, preferentially react at the alkyl group adjacent to the

Full text of DOI:10.1016/0022-328X(95)05569-B

Products guided by the article

Product name:Rh(octaethylporphyrinato)C(O)C₆H₅

Cas No:172226-09-4

R&D Labs maybe for 172226-09-4

Zhonghao (dalian) Research and Design Institute of Chemical Industry Co., Ltd

Contact:+86 411 84674606

Address:201, Huangpu Road , Shahekou District, Dalian ,116023-China
Suzhou Credit International Trading Co., Ltd

Contact:+86-512-65398039

Address:Qingdeng, Hightech. District, Suzhou
Zhejiang kehong chemical co., ltd

Contact:0086-575-85522000

Address:xiner center RD binhai industrial zone shaoxing zhejiang province P.R.China,312073
Hangzhou Ocean Chemical Co., Ltd.

website:http://www.hzoceanchem.com

Contact:+86-571-88025872, 28272092, 28272096

Address:Room 623 ,Building No 1 , COFCO Radius Commercial Center Xiwen Road, Xiacheng District, Hangzhou, Zhejiang Province, China
CHINA MEHECO CORPORATION

Contact:+86-10-67147360/67107388

Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China

Relevant to this article

Bischler-napieralski cyclization-N/C-alkylation sequences for the construction of isoquinoline alkaloids. Synthesis of protoberberines and benzo[c]phenanthridines via C -2′-functionalized 3-arylisoquinolines

Doi:10.1021/jo960007s
(1996)
Doi:10.1007/BF00900422
(1954)
One-pot and efficient synthesis of 5-aminopyrazole-4-carbonitriles catalyzed by potassium phthalimide

Doi:10.3987/COM-16-13623
(2017)
Iron-Mediated Synthesis of Isoxazoles from Alkynes: Using Iron(III) Nitrate as a Nitration and Cyclization Reagent

Doi:10.1021/acs.joc.7b02483
(2018)
Synthesis of bi(cyclohexasilanyl) derivatives

Doi:10.1016/0022-328X(95)05506-K
(1995)
Double stereodifferentiation in the Lewis acid promoted crotylation of (S)-2-alkoxypropanal with chiral β-alkyl (E)-crotylsilanes

Doi:10.1016/0040-4039(95)01895-O
(1995)

Article Doi