Reactions of C-H bonds in organic oxygenates with octaethylporphyrinato rhodium(II) and iridium(II) dimers

DOI: 10.1016/0022-328X(95)05569-B

Source and publish data:

Journal of Organometallic Chemistry p. 47 - 56 (1995)

Update date:2022-08-05

Topics:

Authors:

Rossi, Kenneth J. Del

Zhang, Xiao-Xiang

Wayland, Brandford B.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(95)05569-B

Metalloporphyrin dimers, <(OEP)M>2 (1a, M - Rh; 1b, M = Ir; OEP = octaethylporphyrin dianion), are observed to react with C-H bond units in aldehydes, ketones and benzyl alcohols.Aldehydes, R2CHCHO, preferentially react at the alkyl group adjacent to the

Full text of DOI:10.1016/0022-328X(95)05569-B

Products guided by the article

Product name:Rh(octaethylporphyrinato)C(O)C₆H₅

Cas No:172226-09-4

R&D Labs maybe for 172226-09-4

Jinan Decheng Hemu Medical Technology Co.，Ltd.

Contact:+86-531-68650525

Address:NO.554 Zhengfeng Road High-new Technology Development Zone
Nantong Baokai Chemical Co., Ltd (Hangzhou Baokai Bio-Chemicals Co.,Ltd.)

Contact:+86-513-83886111

Address:No. 68 Suzhou road ,Binjiang Fine Chemical Industrial Park , Beixin town, Qidong city ,Jiangsu province
suzhou chukai pharmateach co,.ltd

Contact:86-512-88812511

Address:Building 3, Wujiang Scientific Innovation Park, 2358 Changan Rd, Wujiang 215200, Jiangsu Province, P. R. China
Chengdu Chengnuo New-Tech Co., Ltd

Contact:0086-028-85749078

Address:4 Jiuyang road,Jiulong industrial port,Chengdu, China
KODI CHEMICAL CO., LTD

Contact:021

Address:Pudong

Relevant to this article

Bischler-napieralski cyclization-N/C-alkylation sequences for the construction of isoquinoline alkaloids. Synthesis of protoberberines and benzo[c]phenanthridines via C -2′-functionalized 3-arylisoquinolines

Doi:10.1021/jo960007s
(1996)
Doi:10.1007/BF00900422
(1954)
One-pot and efficient synthesis of 5-aminopyrazole-4-carbonitriles catalyzed by potassium phthalimide

Doi:10.3987/COM-16-13623
(2017)
Iron-Mediated Synthesis of Isoxazoles from Alkynes: Using Iron(III) Nitrate as a Nitration and Cyclization Reagent

Doi:10.1021/acs.joc.7b02483
(2018)
Synthesis of bi(cyclohexasilanyl) derivatives

Doi:10.1016/0022-328X(95)05506-K
(1995)
Double stereodifferentiation in the Lewis acid promoted crotylation of (S)-2-alkoxypropanal with chiral β-alkyl (E)-crotylsilanes

Doi:10.1016/0040-4039(95)01895-O
(1995)

Article Doi