Tetrahedron Letters p. 7905 - 7908 (1995)
Update date:2022-07-29
Topics:
Hutton
Jolliff
Mitchell
Warren
The natural anti selectivity of the Horner-Wittig reaction with phospine oxides is reduced when there is a branched chain next to the new C=C double bond. A better approach is Luche reduction of the corresponding ketones which gives high anti selectivity when the branched chain is placed on the side chain next to the phosphine oxide.
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