Heterocycles p. 2279 - 2288 (1995)
Update date:2022-09-26
Topics:
Kihara, Masaru
Iwai, Yasumasa
Nagao, Yoshimitsu
3-Phenyl- and 3-alkyl-3-hydroxyindolines were synthesized by intramolecular Barbier reaction of phenyl and alkyl N-(2-iodophenyl)-N-methylaminomethyl ketones with n-BuLi, which were easily prepared from N-methyl-2-iodoaniline and bromomethyl ketones.The treatment of the indolines with acid gave the corresponding indoles in quantitative yields.
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