Polycarbon ligands: Synthesis and characterization of the phosphinodiynes Ph2PC≡C-C≡CR (R = But, Ph, SiMe3),the μ-η1,η2α, β-butadiynyl complexes Ru2(CO)6-(μ-PPh 2

DOI: 10.1139/v96-262

Source and publish data:

Canadian Journal of Chemistry p. 2349 - 2362 (1996)

Update date:2022-08-03

Topics:

Authors:

Blenkiron, Peter

Corrigan, John F.

Pilette, Didier

Taylor, Nicholas J.

Carty, Arthur J.

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Article abstract of DOI:10.1139/v96-262

The phosphino-diynes (PPh₂C≡C-C≡CR) (R = Bu^t, Ph, SiMe₃) are obtained in excellent yield from the corresponding diyne anions RC≡C-C≡C^- by quenching with PPh₂Cl. Monosubstitution on Ru₃(CO)<

Full text of DOI:10.1139/v96-262

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