Tetrahedron Letters p. 741 - 744 (1998)
Update date:2022-08-02
Topics:
Corey
Kania, Robert S.
A short synthesis of (±)-palominol (1) and (±)-dolabellatrienone (2) starting from farnesol is reported. Noteworthy steps include an intramolecular pinacol coupling to form a 15-membered carbocyclic diol and subsequent dianion-accelerated oxy-Cope rearrangement to form the 11,5-trans-fused ring system of the dolabellanes.
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