Tetrahedron Letters p. 8477 - 8480 (1995)
Update date:2022-08-04
Topics:
Lawrence, Nicholas J.
Liddle, John
Jackson, David A.
A range of substituted nitrobenzenes react with the anion of chloromethyldiphenylphosphinoyl oxide to give the substituted nitrobenzyldiphenylphosphine oxide by vicarious nucleophilic substitution.The novel stereoselective synthesis of E-stilbenes via a one-pot vicarious nucleophilic substitution/Horner-Wittig reaction is described.
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