Synthesis of New Chiral Catalysts, Substituted 2-Phenyl-5,6,7,8-tetrahydro-6,6-dimethyl-5,7-methano-quinolines, for the Enantioselective Addition of Diethylzinc to Benzaldehyde

DOI: 10.1016/0957-4166(95)00381-9

Source and publish data:

Tetrahedron Asymmetry p. 2903 - 2904 (1995)

Update date:2022-08-02

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Authors:

Collomb, Phillippe

Zelewsky, Alex von

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Article abstract of DOI:10.1016/0957-4166(95)00381-9

New chiral ligands, substituted 2-phenyl-5,6,7,8-tetrahydro-6,6-dimethyl-5,7-methanoquinolines,were prepared and the catalyzed reaction of diethylzinc with benzaldehyde was studied under various conditions to give 1-phenyl-1-propanol with up to 91percent

Full text of DOI:10.1016/0957-4166(95)00381-9

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Product name:(-)-(1R,5R)-2,3-(2'-Phenyl-1'-azobenzo)-6,6-dimethylbicyclo[3.1.1]heptane

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