Welcome to LookChem.com Sign In|Join Free

Article Doi

Tripodal amido-titanium and -zirconium complexes containing a trisilylsilane-derived ligand framework

DOI: 10.1039/DT9960000125

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 125 - 132 (1996)

Update date:2022-07-29

Topics:

Authors:

Findeis, BerndFindeis, Bernd

Schubart, MartinSchubart, Martin

Gade, Lutz H.Gade, Lutz H.

Moeller, FrankMoeller, Frank

Scowen, IanScowen, Ian

McPartlin, MaryMcPartlin, Mary

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9960000125

A series of amido-titanium and -zirconium complexes containing a tripodal amide with a trisilylsilane ligand framework has been prepared. The primary isolable products in the reaction of SiMe (SiMe2NHR)3 (R = 4-MeC6H4, 2-FC6H4 or 4-MeOC6H4) with LiBun and ZrCl4 in diethyl ether are the [Li(OEt2)2Cl] adducts of which the five-co-ordinate complex [{(4-MeOC6H4NSiMe2) 3MeSi}Zr(μ-Cl)2Li(OEt2)2] and the six-co-ordinate [{(2-FC6H4NSiMe2) 3MeSi}Zr(μ-Cl)2Li(OEt2)2] have been characterised by X-ray crystallography. In the latter one of the fluorine atoms of the peripheral 2-FC6H4 groups is weakly co-ordinated to the metal. Stirring of the (Et2O)2LiCl adducts in toluene generates the four-co-ordinate complexes [Zr{SiMe(SiMe2NR)3}Cl]. Upon reaction of [M{SiMe[SiMe2N(C6H4F-2)]3}Cl] (M = Ti or Zr) with AgO3SCF3 the corresponding triflates were obtained which are sufficiently stable to be isolated. The halide ligand may be readily substituted to give the corresponding methyl, ethynyl and cyclopentadienyl complexes.

View More

Products guided by the article

Product name:[ZrCl2(Li(C4H10O)2)(CH3Si(Si(CH3)2NC6H4CH3)3)]

Cas No:173863-09-7

173863-09-7

R&D Labs maybe for 173863-09-7

Relevant to this article

Hot Product