Towards glycosyl inositol mimics: Stereoselective synthesis of C-α-glucosyl-inositol derivatives via Diels-Alder reactions

DOI: 10.1016/S0040-4039(96)02218-6

Source and publish data:

Tetrahedron Letters p. 73 - 76 (1997)

Update date:2022-08-03

Topics:

Authors:

Jacques, Francis

Dupeyroux, Herve

Joly, Jean-Pierre

Chapleur, Yves

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Article abstract of DOI:10.1016/S0040-4039(96)02218-6

The pentafluorophenyl ester of a C-glucopyranosidyl-linked olefin has proved to be an efficient chiral dienophile for asymmetric Diels-Alder reactions with E-1-acetoxy-1,3-butadiene to give C-α-glucosyl-cyclitol derivatives with excellent regioselectivity but fair diastereoselectivity.

Full text of DOI:10.1016/S0040-4039(96)02218-6

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