Bulletin of the Chemical Society of Japan p. 3665 - 3666 (1982)
Update date:2022-07-31
Topics:
Koto, Shinkiti
Inada, Shigeru
Narita, Tomoko
Morishima, Naohiko
Zen, Shonosuke
Some mixed acetal glycosides were stereoselectively synthesized by the reaction of 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitroanilino)-α-D-glucopyranosyl bromide with alcohols in acetone containing Hg(CN)2, HgBr2, and tetrabutylammonium bromide at room temperature.When t-butyl alcohol was used, a novel enol glycoside of acetone was formed.
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Doi:10.1021/jo951832w
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