Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy p. 2019 - 2026 (1995)
Update date:2022-08-05
Topics:
Ludwig, C.
Goetze, H.-J.
The FT Raman and infrared spectra of triphenylbismuth (C6H5)3Bi and the perdeuterated molecule (C6D5)3Bi have been measured in the range 3600-100 cm-1.A normal coordinate analysis has been performed for both substances using a modified valence force field.This leads to a complete assignment of all 96 vibrations of each of the two compounds.The complete molecule with 34 atoms and C1 symmetry is calculated for the first time.Out-of-plane and in-plane vibrations are computed together in one step.For the perdeuterated isotopomer (2)H NMR, (13)C NMR and MS date are also given.
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