
Journal of Fluorine Chemistry p. 227 - 232 (1993)
Update date:2022-08-02
Topics:
Brunet, Sylvette
Batiot, Catherine
Barrault, Joeel
Blanchard, Michel
Coustard, Jean-Marie
During the liquid-phase fluorination of 1,1,1-trichloroethane with SbCl5*HF, 1,1-dichloroethene is formed.This reacts to give linear and branched oligomers.The hydrolysis of these by-products affords 3,5-dichlorophenol, 6-methyl-4-chloro-2-pyran-2-one and 2-methyl-5,7-dichlorochromone whose source is the acid-catalyzed reaction of water with the trimer and pentamer of 1,1-dichloroethene.
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