[Cu(H2dppd)(η1-OClO3)]ClO4: The first crystallographically characterized phosphine complex of copper(II) {H2dppd = N,N′-bis[2-(diphenylphosphino)phenyl]propane-1,3-diamine}

Article abstract of DOI:10.1039/CC9960000433

The title complex 2, easily obtained by controlled potential oxidation of the copper(I) precursor [Cu(H₂dppd)]BF₄ 1, in perchlorate medium, crystallizes as a C₆H₆ monosolvate from dichloroethane-benzene, (2a), or as a CH₂Cl₂ hemisolvate from dichloromethane-toluene (2b), to give dark-red crystals which have been structurally characterized by X-ray crystallography.

Full text of DOI:10.1039/CC9960000433

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