
Tetrahedron Letters p. 1237 - 1240 (1996)
Update date:2022-08-03
Topics: 1,4-addition NMR spectroscopy Mass spectrometry Reaction Conditions Acrylonitrile
Dupraz, Agnes
Guy, Philippe
Dupuy, Claude
The very hydrophilic primary polyols pentaerythritol (PE), 1,1,1-tris(hydroxymethyl)ethane and tris(hydroxymethyl)aminomethane (TRIS), can be polyetherified in satisfactory yield by 1,4-addition to tert-butyl acrylate using phase-transfer catalysis. Polycyanoethylation of these polyols can also be accomplished with acrylonitrile. Preliminary results of chelation between some polyether-acids with samarium(III) are presented.
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