Enantioselective Ring Cleavage of meso-Epoxides with B-Halodiisopinocampheylboranes

DOI: 10.1021/ja00226a050

Source and publish data:

Journal of the American Chemical Society p. 6246 - 6248 (1988)

Update date:2022-08-04

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Authors:

Joshi, N. N.

Srebnik, M.

Brown, Herbert C.

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Article abstract of DOI:10.1021/ja00226a050

Asymmetric synthesis starting from meso compounds is an increasingly important method for the preparation of optically active compound.We now report the synthesis of optically active 1,2-halohydrins using B-halodiisopinocampheylboranes, Ipc2BX (1a-c).

Full text of DOI:10.1021/ja00226a050

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