Synthesis of azasugars. Part 2: Isomerization of polyhydroxylated azepanes

DOI: 10.1016/0040-4039(96)00097-4

Source and publish data:

Tetrahedron Letters p. 1613 - 1616 (1996)

Update date:2022-07-29

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Authors:

Poitout, Lydie

Le Merrer, Yves

Depezay, Jean-Claude

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Article abstract of DOI:10.1016/0040-4039(96)00097-4

Isomerization of enantiopure C₂-symmetric 3,5-dihydroxyazepane derivatives has been studied. The neighboring nitrogen participation occurs during mesylation to give a chloromethyl-piperidine, whereas from the L-ido-azepane a chiral bridged morp

Full text of DOI:10.1016/0040-4039(96)00097-4

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