Preparation and characterization of O,O′-dialkyldithiophosphate complexes of methylplatinum(II)

Article abstract of DOI:10.1016/0277-5387(95)00415-7

The reaction of [PtMe(X)(COD)] (X = Cl, I) with 1 mole equivalent of NH₄ SSP(OR′)₂ gave [{Pt(Me)SSP(OR′)₂}₂COD] (R′ = Et or Prⁱ). The latter complexes on treatment with tertiary phosphines afforded [P