Tetrahedron Letters p. 2317 - 2320 (1996)
Update date:2022-08-04
Topics:
Schnapp, Karlyn A.
Motz, Philip L.
Stoeckel, Sharon M.
Wilson, R. Marshall
Krause Bauer, Jeanette A.
Bohne, Cornelia
The photochemistry of sterically hindered enones 1 and 2 is described. A novel photorearrangement occurs in both systems which involves carbonyl attack on the adjacent phenyl ring, expansion of that ring to a cycloheptatriene and subsequent photochemically induced 1,7-phenyl migration.
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(1996)
