Synthesis of enantiopure cis-decalins from microbially-derived cis- 1,2-dihydrocatechols

DOI: 10.1039/cc9960000869

Source and publish data:

Chemical Communications p. 869 - 870 (1996)

Update date:2022-07-29

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Authors:

Banwell, Martin G.

Dupuche, Joseph R.

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Article abstract of DOI:10.1039/cc9960000869

The microbially-derived cis-1,2-dihydrocatechol 3 is converted, via reaction sequences involving Diels-Alder cycloaddition and anionic oxy-Cope rearrangement steps, into the enantiopure cis-decalins 15 and 26; using simple modifications of this chemistry

Full text of DOI:10.1039/cc9960000869

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