Ancillary ligand effects in organoyttrium chemistry: Synthesis, characterization, and electronic structure of Bis(benzamidinato)yttrium compounds

Article abstract of DOI:10.1021/om950813+

The synthesis of [PhC(NSiMe₃)₂]₂Y(μ-Cl) ₂Li·2THF (1) from YCl₃·3.5THF and [PhC-(NSiMe₃)₂]Li, which is easily transformed into [PhC(NSiMe₃)₂]₂YCl·

Full text of DOI:10.1021/om950813+

Organometallics 1996, 15, 2279-2290
2279
An cilla r y Liga n d Effects in Or ga n oyttr iu m Ch em istr y:
Syn th esis, Ch a r a cter iza tion , a n d Electr on ic Str u ctu r e of
Bis(ben za m id in a to)yttr iu m Com p ou n d s
Robbert Duchateau, Cornelis T. van Wee, Auke Meetsma,
Piet Th. van Duijnen, and J an H. Teuben*,†
Groningen Center for Catalysis and Synthesis, Department of Chemistry,
University of Groningen, Nijenborgh 4, NL-9747 AG Groningen, The Netherlands
Received October 13, 1995X
The synthesis of [PhC(NSiMe3)2]2Y(µ-Cl)2Li‚2THF (1) from YCl3‚3.5THF and [PhC-
(NSiMe3)2]Li, which is easily transformed into [PhC(NSiMe3)2]2YCl‚THF (2), provides a useful
entry into the chemistry of several bis(N,N′-bis(trimethylsilyl)benzamidinato)yttrium
complexes. Those prepared from 2 by chloride metathesis include [PhC(NSiMe3)2]2YR (R )
BH4‚THF (3), N(SiMe3)2 (4), 2,6-(CMe3)2-4-MeOC6H2 (5), (µ-Me)2Li‚TMEDA (6) (TMEDA )
N,N,N′,N′-tetramethylethylenediamine), CH2Ph‚THF (7), CH(SiMe3)2 (8)). Similar to 8,
[p-MeOC6H4C(NSiMe3)2]2YCH(SiMe3)2 (8OMe) could be prepared starting from [p-MeOC6H4C-
(NSiMe3)2]2YCl‚THF (2OMe). Hydrogenolysis (4 atm) of 8 and 8OMe affords dimeric hydrides
{[p-X-C6H4C(NSiMe3)2]2Y(µ-H)}2 (X ) H (9), X ) MeO (9OMe)). The alkyl 8OMe and the hydride
9 have been characterized by an X-ray diffraction structure determination. Sterically the
bis(N,N′-bis(trimethylsilyl)benzamidinate) ligand system resembles more the bis(penta-
methylcyclopentadienyl) than the bis(cyclopentadienyl) ligand set. However, INDO/1 semi-
empirical MO studies indicate that the electronic properties of [HC(NH)2]2YCH3 (used as a
model for bis(benzamidinato)yttrium alkyl complexes) are rather different from [C5H5]2YCH3.
The yttrium atom in [HC(NH)2]2YCH3 is considerably more positively charged than in [C5H5]2-
YCH3. The resulting strong ionic character of the bis(benzamidinate) system is held
responsible for the absence of agostic interactions and H/D exchange and the low hydro-
genolysis rate observed.
In tr od u ction
hydride species, Cp*2LnR (Cp* ) η5-C5Me5; Ln ) Sc,
Y, La, Ce, Nd, Sm, Lu; R ) CH(SiMe3)2, Me, H)2 have
been shown to be active, either as catalysts or as
stoichiometric reagents, in selective C-C and C-H bond
formation and in C-H/C-X bond activation. Typical
examples are found in olefin (oligo/polymerization,2,3
hydrogenation,4a,b hydroboration,4c hydrosilylation,4d
amino-olefin hydroamination/cyclization4e) and in alkyne
(oligomerization,2,5a-c hydrogenation,5c hydroamination/
cyclization5d) transformations. Linking the cyclopenta-
dienyl ligands and/or varying the cyclopentadienyl
substituents has in most cases led to higher catalytic
activity.6 Recently, there has been an increased atten-
tion for other spectator ligands whether as alternatives
for, or in addition to, (pentamethyl)cyclopentadienyl
groups. Among the systems that have appeared are
cyclopentadienyl ligands with a pendant amido or
alkoxo functionality,7 porphyrins,8 pyrazolylborates,9
aryloxides,10 carboranes11 and amidodiphosphines.12
Group 3 metal and organolanthanide compounds have
been at the center of scientific attention for over a
decade.1 Among the most interesting aspects of this
chemistry is that group 3 metal and lanthanide com-
pounds appear to be of great importance in homoge-
neous catalysis of C-H, C-C, and C-X bond
formation.2-5 Until now most of the work reported was
on compounds stabilized by bis(pentamethylcyclopenta-
dienyl) or closely related ligand systems. Alkyl and
† E-mail address: TEUBEN@rugch4.chem.rug.nl
X Abstract published in Advance ACS Abstracts, April 15, 1996.
(1) (a) Evans, W. J . Adv. Organomet. Chem. 1985, 24, 131. (b) Evans,
W. J . Polyhedron 1987, 6, 803. (c) Schaverien, C. J . Adv. Organomet.
Chem. 1994, 36, 289.
(2) (a) Thompson, M. E.; Baxter, S. M.; Bulls, A. R.; Burger, B. J .;
Nolan, M. C.; Santarsiero, B. D.; Schaefer, W. P.; Bercaw, J . E. J . Am.
Chem. Soc. 1987, 109, 203. (b) Den Haan, K. H.; Wielstra, Y.; Teuben,
J . H. Organometallics 1987, 6, 2053. (c) J eske, G.; Lauke, H.;
Mauermann, H.; Swepston, P. N.; Schumann, H.; Marks, T. J . J . Am.
Chem. Soc. 1985, 107, 8091. (d) Heeres, H. J .; Renkema, J .; Booij, M.;
Meetsma, A.; Teuben, J . H. Organometallics 1988, 7, 2495. (e) Evans,
W. J .; Chamberlain, L. R.; Ulibarri, T. A.; Ziller, J . W. J . Am. Chem.
Soc. 1988, 110, 6423. (f) Watson, P. L. J . Chem. Soc., Chem. Commun.
1983, 276. (g) Watson, P. L. J . Am. Chem. Soc. 1983, 105, 6491.
(3) Burger, B. J .; Thompson, M. E.; Cotter, W. D.; Bercaw, J . E. J .
Am. Chem. Soc. 1990, 112, 1566.
Our exploration of yttrium complexes with alternative
spectator ligand systems is aimed at comparing the
reactivity of these compounds with that of bis(penta-
(4) (a) J eske, G.; Lauke, H.; Mauermann, H.; Schumann, H.; Marks,
T. J . J . Am. Chem. Soc. 1985, 107, 8111. (b) Molander, G. A.; Hoberg,
J . O. J . Org. Chem. 1992, 57, 3266. (c) Harrison, K. N.; Marks, T. J . J .
Am. Chem. Soc. 1992, 114, 9220. (d) Sakakura, T.; Lautenschlager,
H.-J .; Tanaka, M. J . Chem. Soc., Chem. Commun. 1991, 40. (e) Gagne´,
M. R.; Stern, C. L.; Marks, T. J . J . Am. Chem. Soc. 1992, 114, 275.
(5) (a) Heeres, H. J .; Heeres, A.; Teuben, J . H. Organometallics 1990,
9, 1508. (b) Heeres, H. J .; Teuben, J . H. Organometallics 1991, 10,
1980. (c) St. Clair, M.; Schaefer, W. P.; Bercaw, J . E. Organometallics
1991, 10, 525. (d) Li, Y.; Fu, P.-F.; Marks, T. J . Organometallics 1994,
13, 439.
(6) (a) J eske, G.; Schock, L. E.; Swepston, P. N.; Schumann, H.;
Marks, T. J . J . Am. Chem. Soc. 1985, 107, 8103. (b) Bunel, E.; Burger,
B. J .; Bercaw, J . E. J . Am. Chem. Soc. 1988, 110, 976. (c) Stern, D.;
Sabat, M.; Marks, T. J . J . Am. Chem. Soc. 1990, 112, 9558. (d) Gagne´,
M. R.; Brard, L.; Conticello, V. P.; Giardello, M. A.; Stern, C. L.; Marks,
T. J . Organometallics 1992, 11, 2003. (e) Coughlin, E. B.; Bercaw, J .
E. J . Am. Chem. Soc. 1992, 114, 7606. (f) Conticello, V. P.; Brard, L.;
Giardello, M. A.; Tsuji, Y.; Sabat, M.; Stern, C. L.; Marks, T. J . J . Am.
Chem. Soc. 1992, 114, 2761. (g) Hajela, S.; Bercaw, J . E. Organo-
metallics 1994, 13, 1147.
S0276-7333(95)00813-2 CCC: $12.00 © 1996 American Chemical Society

2280 Organometallics, Vol. 15, No. 9, 1996
Duchateau et al.
delocalized within the NCN fragment through π-bond-
ing of the C-pπ and N-pπ orbitals, giving a very stable
diazaallylic ligand which is normally σ,σ′-bonded to the
metal (4 e- donor, Figure 1B).15-17 This charge delocal-
ization makes the ligand essentially insensitive for
nucleophilic attack. Furthermore, partial electron do-
nation from the benzamidinate π-system to the metal
center may occur (Figure 1C), as is often observed for
amido and alkoxo complexes.19 In general, the ligand
is bonded to one metal center, although a few examples
of binuclear complexes with bridging N,N′-bis(trimeth-
ylsilyl)benzamidinate ligands are known as well.20
In this paper the synthesis and characterization of a
range of bis(N,N′-bis(trimethylsilyl)benzamidinato)-
yttrium derivatives is described, together with the
molecular structures of [p-MeOC6H4C(NSiMe3)2]2YCH-
(SiMe3)2 and {[PhC(NSiMe3)2]2Y(µ-H)}2. The stabilizing
ability of the bis(N,N′-bis(trimethylsilyl)benzamidinate)
ligand system is clearly illustrated by the fact that alkyl
and hydrido species are well accessible. In a separate
section, the steric and electronic properties of the bis-
(benzamidinate) system are compared with those of the
extensively investigated bis((pentamethyl)cyclopenta-
dienyl) system.
F igu r e 1. Possible bonding modes of the benzamidinate
ligands: A, σ-bonded; B, σ,σ′-bonded; C, σ,σ + π-bonded.
methylcyclopentadienyl) and related systems. When
deciding which direction to go, we argued that replacing
cyclopentadienyls by hard Lewis basic ligands such as
alkoxides or amides would render the metal center more
electron deficient. This is expected to increase the
polymerization activity for R-olefins. Chain termination
by â-hydrogen transfer will be suppressed, since the
alkyl compound will be thermodynamically prefered
relative to the hydride olefin complex.13 Furthermore,
decreasing electron density at the metal center in
cationic ethylene-bridged bis(indenyl)zirconium systems
has been found to increase the stereoselectivity of
propylene insertion.14
We decided to focus on hard basic benzamidinate
anions as alternatives for (pentamethyl)cyclopenta-
dienyl ligands. The pioneering work of Dehnicke,15
Roesky,16 and Edelmann17 with N,N′-bis(trimethylsilyl)-
benzamidinate has shown that this ligand can coordi-
nate to a large variety of metal centers in different
bonding modes (Figure 1). So far, however, no reports
have been made of the use of benzamidinates as
stabilizing ligands in catalysis.
Resu lts a n d Discu ssion
Gen er a l Con sid er a tion s. (a ) Syn th esis. Intro-
duction of N,N′-bis(trimethylsilyl)benzamidinate ligands
is conveniently achieved through salt metathesis. Reac-
tion of YCl3‚3.5THF with 2 equiv of [PhC(NSiMe3)2]Li
in THF results in the monochloride complexed with
LiCl‚2THF, [PhC(NSiMe3)2]2YCl2Li‚2THF (1, Scheme
1). Attempts to remove the LiCl and THF by sublima-
tion of 1 failed due to thermal decomposition. However,
the LiCl can easily be cleaved off in refluxing pentane
yielding the THF adduct, [PhC(NSiMe3)2]2YCl‚THF (2),
an excellent precursor to a wide range of derivatives
(Scheme 1). Substitution of the chloride proceeds es-
sentially quantitatively on treatment with the indicated
reagent in either ether or toluene, affording salt free
and pentane soluble products. However, the high
solubility of most complexes hampers their purification.
Not surprising for small substituents, the coordination
sphere of the Lewis acidic metal center is completed
Apart from a few exceptions (Figure 1A),18 the nega-
tive charge of the benzamidinate ligand appears fullly
(7) (a) Shapiro, P. J .; Cotter, W. D.; Schaefer, W. P.; Labinger, J .
A.; Bercaw, J . E. J . Am. Chem. Soc. 1994, 116, 4632. (b) Fandos, R.;
Meetsma, A.; Teuben, J . H. Organometallics 1991, 10, 59. (c) Hughes,
A.; Meetsma, A.; Teuben, J . H. Organometallics 1993, 12, 1936. (d)
Trouve´, G.; Laske, D.; Meetsma, A.; Teuben, J . H. J . Organomet.
Chem., in press.
(8) (a) Schaverien, C. J .; Orpen, A. G. Inorg. Chem. 1991, 30, 4968
and references cited therein. (b) Arnold, J .; Hoffman, C. G.; Dawson,
D. Y.; Hollander, F. J . Organometallics 1993, 12, 3645.
(9) For an overview see: Trofimenko, S. Chem. Rev. 1993, 93, 943.
(10) (a) Schaverien, C. J .; Meijboom, N.; Orpen, A. G. J . Chem. Soc.,
Chem. Commun. 1992, 124. (b) Schaverien, C. J . Organometallics 1994,
13, 69.
(11) For an overview see: Saxena, A. K.; Hosmane, N. S. Chem. Rev.
1993, 93, 1081.
(12) (a) Fryzuk, M. D.; Haddad, T. S. J . Am. Chem. Soc. 1988, 110,
8263. (b) Fryzuk, M. D.; Haddad, T. S.; Rettig, S. J . Organometallics
1991, 10, 2026. (c) Fryzuk, M. D.; Haddad, T. S.; Rettig, S. J .
Organometallics 1992, 11, 2967.
either by forming “ate” complexes [PhC(NSiMe3)2]2Y(µ-
1
X)2Li‚2L (1, X ) Cl, L ) THF; 6, X ) Me, L )
/
2
TMEDA) or by complexation of solvent molecules [PhC-
(NSiMe3)2]2YX‚THF (2, X ) Cl; 3, X ) BH4; 7, X ) CH2-
Ph). Solvent-free neutral complexes, [PhC(NSiMe3)2]2-
YX (4, X ) N(SiMe3)2; 5, X ) O-2,6-(CMe3)2-4-MeC6H2;
8, X ) CH(SiMe3)2) can be made only when sterically
demanding substituents are employed. Reaction of 2
with small alkylating reagents, RM (M ) Li, R ) Me,
Et, CH2SiMe3, CH2CMe3; M ) K, R ) CH2Ph) is
(13) (a) Bruno, J . W.; Stecher, H. A.; Morss, L. R.; Sonnenberger,
D. C.; Marks, T. J . J . Am. Chem. Soc. 1986, 108, 7275. (b) Labinger,
J . A.; Bercaw, J . E. Organometallics 1988, 7, 926.
(14) Lee, I.-M.; Gauthier, W. J .; Ball. J . M.; Iyengar, B.; Collins, S.
Organometallics 1992, 11, 2115.
(15) For example see: (a) Dehnicke, K.; Ergezinger, C.; Hartmann,
E.; Zinn. A.; Ho¨sler, K. J . Organomet. Chem. 1988, 352, C1. (b) Fenske,
D.; Hartmann, E.; Dehnicke, K. Z. Naturforsch. 1988, 43b, 1611.
(16) Roesky, H. W.; Meller, B.; Noltemeyer, M.; Schmidt, H.-G.;
Scholz, U.; Sheldrick, G. M. Chem. Ber. 1988, 121, 1403.
(17) For example see: (a) Recknagel, A.; Kno¨sel, F.; Gornitzka, H.;
Noltemeyer, M.; Edelmann, F. T. J . Organomet. Chem. 1991, 417, 363.
(b) Wedler, M.; Recknagel, A.; Gilje, J . W.; Noltemeyer, M.; Edelmann,
F. T. J . Organomet. Chem. 1992, 426, 295. (c) Wedler, M.; Kno¨sel, F.;
Edelmann, F. T.; Behrens, U. Chem. Ber. 1992, 125, 1313.
(18) The only report of a benzamidinate acting as a 2 electron donor
is in bis(N,N′-bis(trimethylsilyl)benzamidinato)mercury, [PhC(NSiMe3)2]2-
Hg, where delocalization of the charge within the NCN fragment is
negligible as is illustrated by the C-N bond distances which are
comparable to those found in N,N,N′-tris(trimethylsilyl)benzamidine,
PhC(NSiMe3)N(SiMe3)2: (a) Zinn, A.; Dehnicke, K.; Fenske, D.; Baum,
G. Z. Z. Anorg. Allg. Chem. 1991, 596, 47. (b) Ergezinger, C.; Weller,
F.; Dehnicke, K. Z. Naturforsch. 1988, 43b, 1119.
(19) (a) Schaverien, C. J .; Frijns, J . H. G.; Heeres, H. J .; van den
Hende, J . R.; Teuben, J . H.; Spek, A. L. J . Chem. Soc., Chem. Commun.
1991, 642. (b) Bradley, D. C.; Ghotra, J . S.; Hart, F. A.; Hursthouse,
M. B.; Raithby, P. R. J . Chem. Soc., Dalton Trans. 1977, 1166. (c)
Aspinall, H. C.; Bradley, D. C.; Hursthouse, M. B.; Sales, K. D.; Walker,
N. P. C.; Hussain, B. J . Chem. Soc., Dalton Trans. 1989, 623. (d)
Aspinall, H. C.; Moore, S. R.; Smith, A. K. J . Chem. Soc., Dalton Trans.
1992, 153. (e) Allen, M.; Aspinall, H. C.; Moore, S. R.; Hursthouse, M.
B.; Karvalov, A. I. Polyhedron 1992, 11, 409.
(20) (a) Maier, S.; Hiller, W.; Stra¨hle, J .; Ergezinger, C.; Dehnicke,
K. Z. Naturforsch. 1988, 43b, 1628. (b) Fenske, D.; Baum, G.; Zinn,
A.; Dehnicke, K. Z. Naturforsch. 1990, 45b, 1273. (c) Zinn, A.; Weller,
F.; Dehnicke, K. Z. Allg. Anorg. Chem. 1991, 594, 106.

Bis(benzamidinato)yttrium Compounds
Organometallics, Vol. 15, No. 9, 1996 2281
Sch em e 1a
a
(i) THF; (ii) pentane, reflux; (iii) LiBH4, toluene; (iv) NaN(SiMe3)2, toluene; (v) LiOAr, toluene; (vi) MeLi‚TMEDA, ether; (vii)
KCH2Ph, toluene; (viii) LiCH(SiMe3)2, toluene.
complicated due to both incorporation of solvent mol-
ecules and of LiCl, yielding mixtures of products.
Among these small alkylating reagents, only MeLi and
PhCH2K gave well-defined products, [PhC(NSiMe3)2]2Y(µ-
Me)2Li‚TMEDA (6) and [PhC(NSiMe3)2]2YCH2Ph.THF
(7), respectively.
Attempts to synthesize a neutral methyl complex by
reaction of 2 with 1 equiv of MeLi were unsuccessful
and so was the attempted removal of the THF molecule
in the solvated benzyl complex, 7.21 To structurally
compare 8 with the analogous Cp*2YCH(SiMe3)2, it was
attempted to grow single crystals of 8 for X-ray crystal
structure analysis. Due to the extremely high solubility,
it appeared to be impossible to recrystallize 8 from
pentane. To solve this problem, the less soluble para-
methoxy-substituted benzamidinate ligand, p-MeOC6-
H4C(NSiMe3)2, was introduced. Substitution at the
para-position does not essentially influence the sterics
of the ligand. Moreover, the dihedral angle between the
phenyl ring and the NCN plane of the benzamidinate
ligand typically ranges from 60 to 90°,22 precluding
effective conjugation between both π-systems. As a
result, substitution at the para-position of the benz-
amidinate phenyl group is not expected to have a large
electronic influence either. Similar to the syntheses of
2 and 8, [p-MeOC6H4C(NSiMe3)2]2YCl‚THF (2OMe) and
[p-MeOC6H4C(NSiMe3)2]2YCH(SiMe3)2 (8OMe) could be
prepared in high yield. Repeated recrystallization of
8OMe yielded single crystals suitable for X-ray analysis
(vide infra).
(b) Ch a r a cter iza tion . All complexes (2-8) are
stable at room temperature and show no thermal
decomposition in benzene after 24 h at 100 °C, but they
are extremely oxygen and moisture sensitive. Spectro-
scopic and analytical data are presented in the Experi-
mental Section, and only a number of interesting
features and general trends will be discussed here. The
benzamidinate NMR resonances are not very diagnostic
for identification and assignment purposes. The phenyl
(21) (a) In an attempt to prepare a neutral methyl complex, reactions
of 2 with 1 equiv of MeLi were carried out in different solvents
(pentane, ether, toluene, THF). (b) In attempts to remove the coordi-
nated THF in 7, the compound was gently warmed (50 °C) in vacuo.
This did not lead to release of the THF, whereas sublimation
exclusively led to decomposition of the compound.
(22) (a) Fenske, D.; Hartmann, E.; Dehnicke, K. Z. Naturforsch.
1988, 43b, 1611. (b) Ergezinger, C.; Weller, F.; Dehnicke, K. Z.
Naturforsch. 1988, 43b, 1119.

2282 Organometallics, Vol. 15, No. 9, 1996
Duchateau et al.
Ta ble 1. Selected Bon d Dista n ces a n d An gles for
[p-MeOC6H4C(NSiMe3)2]2YCH(SiMe3)2 (8OMe
)
Distances (Å)
Y(1)-N(1)
Y(1)-N(2)
Y(1)-N(3)
Y(1)-N(4)
Y(1)-C(1)
2.344(3)
2.325(4)
2.345(4)
2.336(3)
2.718(5)
Y(1)-C(15)
Y(1)-C(29)
N(1)-C(1)
N(2)-C(1)
C (29)-H(29)
2.733(5)
2.431(5)
1.331(6)
1.342(6)
1.092(4)
Angles (deg)
58.85(12) C(15)-Y(1)-C(29) 117.76(15)
N(1)-Y(1)-N(2)
N(3)-Y(1)-N(4)
58.50(12) Y(1)-C(29)-Si(5)
115.6(2)
116.1(2)
92.0(2)
C(1)-Y(1)-C(15) 122.71(13) Y(1)-C(29)-Si(6)
C(1)-Y(1)-C(29) 119.23(14) Y(1)-C(29)-H(29)
1
1
borohydrides (δ 1.32 ppm, q, J B-H ) 80 Hz) in the H
NMR spectrum indicates fast exchange of terminal and
bridging hydrides in solution. In contrast to the analo-
gous Cp*2Y(µ-Me)2Li‚(OEt2)2 (δ -1.80, 2J Y-H ) 2.0 Hz),24
no yttrium coupling to the methyl groups is observed
for 6. Unlike Cp*2YCH2Ph,25 the absence of highfield
resonances for the ortho-protons of the benzyl group in
the 1H NMR spectrum of 7, together with the large
coupling constant of the R-carbon (1J C-H ) 118 Hz),26
indicates that γ-agostic interaction of the benzyl group
is not important, which is not unexpected for a THF
adduct. As observed for all group 3 metal and lan-
thanide bis(trimethylsilyl)methyl complexes known, the
small C-H coupling on the R-carbon in 8 (1J C-H ) 88
Hz) and 8OMe (1J C-H ) 88 Hz) suggests an R-agostic
interaction of the carbyl C-H bond with yttrium.26
However, one cannot discard the possibility that the
hybridization of the R-C atom in bis(trimethylsilyl)-
methyl systems, [Ln]-CH(SiMe3)2, reflects the steric
strain between the large bulk of the SiMe3 substituents
and the ancillary ligand system, forcing the R-carbon
to adopt a planar geometry.
Another remarkable aspect is the significant down-
field shift of the R-carbon resonance in the 13C NMR
spectrum (δ 43.5 ppm) and of the yttrium resonance in
the 89Y NMR spectrum (δ 721 ppm) of 8, compared with
Cp*2YCH(SiMe3)2 (13C, 25.2 ppm; 89Y, 79 ppm).19a,27
Replacement of a cyclopentadienyl by more electro-
negative σ-donor ligands (alkoxide, amide, alkyl) invari-
ably leads to deshielding of the metal and R-carbon
nucleus.10b,19a,28 Although tempting, extreme care should
be taken when correlating chemical shifts (13C and 89Y)
and the electrophilicity of the metal center, since
electrophilicity of the metal center is not the only effect
that influences the chemical shift.28
F igu r e 2. ORTEP drawing of [p-MeOC6H4C(NSiMe3)2]2-
YCH(SiMe3)2 (8OMe). Hydrogen atoms (except H(29)) are
omitted for clarity.
1H NMR resonances form a multiplet while the single
trimethylsilyl resonance hardly shifts within the range
of complexes (1H: δ ) 0.03 (5)-0.21 (6) ppm). For all
compounds, the single resonance in the 1H and 13C NMR
spectra for the benzamidinate trimethysilyl substituents
indicates fast fluxional behavior of the ligands around
the metal at room temperature. For this equilibration,
several mechanisms can be proposed. One possibility,
suggested by Edelmann et al., is temporary loss of the
bidentate character of the benzamidinate ligands fol-
lowed by rotation around the Y-N bond.17c Another
possibility is simultaneous cogwheel type rotation of
both benzamidinate ligands around their Y-C axes, i.e.
without one of the ligating nitrogen atoms being loos-
ened. Upon cooling, the single benzamidinate-SiMe3
resonance splits into two distinct, equi-intense singlets
which can be assigned to equatorial and axial SiMe3
groups (Figure 2). From the coalescence temperatures
and the ∆νc of the two benzamidinate-SiMe3 singlets
at the low temperature extreme, the Gibbs energy for
rotation for this process in 4 and 6 was calculated (4,
∆Gq ) 57 ( 1 kJ ‚mol-1; 6, ∆Gq ) 39 ( 1 kJ ‚mol-1).
Tc
Tc
Assuming that the bonding of the benzamidinate ligands
is comparable in both complexes, the different fluxion-
ality (∆G‡Tc) in these complexes can be attributed to
different steric interactions of the various ligands. For
the pentacoordinated amido complex 4, rotation of the
benzamidinato ligands is clearly more hindered than for
the hexacoordinated alkyl compound 6. This is in
agreement with the larger steric bulk of the N(SiMe3)2
fragment compared to the (µ-Me)2Li‚TMEDA group.
A satisfactory elemental analysis of 1 could not be
obtained due to (partial) loss of solvent (THF). The
complex was characterized by 1H and 13C NMR and then
converted into 2. The chloride 2 contains 0.25 equiv of
pentane in the crystal lattice (NMR, elemental analysis),
which can be removed completely by warming at 50 °C
in vacuo for 24 h, leaving an amorphous white solid.
The B-H vibration bands in the IR spectrum of 3 do
not give conclusive information about the bonding mode
of the BH4 group.23 However, η2-(µ-H)2BH2 or η3-(µ-H)3-
BH bonding is likely.23 The single resonance for the
To get more insight into the geometry of 8OMe, a low-
temperature X-ray structure determination was carried
out. An ORTEP drawing of 8OMe is shown in Figure 2
and selected bond distances and angles are listed in
Table 1. Details concerning the data collection are listed
in Table 5. The high quality of the data set allowed
solution and refinement of all hydrogen atom positions.
(24) Den Haan, K. H.; Wielstra, Y.; Eshuis, J . J . W.; Teuben, J . H.
J . Organomet. Chem. 1987, 323, 181.
(25) (a) Booij, M.; Deelman, B.-J .; Duchateau, R.; Postma, D. S.;
Meetsma, A.; Teuben, J . H. Organometallics 1993, 12, 3531. (b) Booij,
M. Ph.D. Thesis, University of Groningen, 1989.
(26) (a) Brookhart, M.; Green, M. L. H. J . Organomet. Chem. 1983,
250, 395. (b) Green, J . C.; Payne, M. P. Magn. Reson. Chem. 1987, 25,
544. (c) J ordan, R. F.; LaPointe, R. E.; Bajgur, C. S.; Echols, S. F.;
Willett, R. J . Am. Chem. Soc. 1987, 109, 4111.
(27) Den Haan, K. H.; de Boer, J . L.; Teuben, J . H.; Spek, A. L.;
Kojic-Prodic, B.; Hays, G. R.; Huis, R. Organometallics 1986, 5, 1726.
(28) Duchateau, R.; Teuben, J . H.; Frijns, J . H. G.; Budzelaar, P.
H. M. to be published.
(23) (a) Gun’ko, Y. K.; Bulychev, B. M.; Solovechick, G. L.; Belsky,
V. K. J . Organomet. Chem. 1992, 424, 289. (b) Laske, D. A.; Duchateau,
R.; Teuben, J . H.; Spek, A. L. J . Organomet. Chem. 1993, 462, 149. (c)
Marks, T. J .; Kolb, J . R. Chem. Rev. 1977, 77, 263. (d) Marks, T. J .;
Kennely, W. J . Inorg. Chem. 1972, 11, 2540.

Bis(benzamidinato)yttrium Compounds
Organometallics, Vol. 15, No. 9, 1996 2283
Ta ble 2. Selected Bon d Dista n ces a n d An gles for
353.5(2)°). The position of the R-H, H(29), could not be
determined with high accuracy, but in contrast to
Cp*2YCH(SiMe3)2,27 there is no indication that H(29)
is forming a strong R-agostic interaction with the
yttrium atom. In addition, the large obtuse and identi-
cal Y-C-Si angles (115-116o) in 8OMe also exclude
other agostic (γ, δ) interactions with other parts of the
bis(trimethylsilyl)methyl ligand, in contrast to what has
been observed in Cp*2LnCH(SiMe3)2 (Ln ) Y,27 Ce,2d
Nd2c) and [Me2Si(C5Me4)(C5R4)]2LnCH(SiMe3)2 (Ln )
Nd, R ) Me;6a Ln ) Lu, R ) H6c) systems. Assuming
that benzamidinate ligands are 4 electron donors, the
absence of agostic interactions in the formally 10
electron complex 8OMe is rather surprising. Similarly,
[OEP]YCH(SiMe3)2 (OEP ) octaethylporphyrin) did not
show any agostic interactions either.8a One feature that
8OMe and [OEP]YCH(SiMe3)2 have in common is that
both complexes are stabilized by nitrogen-based hard
Lewis basic ancillary ligands. A possible explanation
for the absence of agostic interactions in these complexes
is that these hard basic ligands render the complexes
significantly more ionic. The empty yttrium orbitals
will be more contracted on the metal and therefore less
available for effective overlap with C-H or C-Si
electron pairs (vide infra).
{[P h C(NSiMe3)2]2Y(µ-H)}2 (9)
Distances (Å)
Y(1)-N(1)
Y(1)-N(2)
Y(1)-N(3)
Y(1)-N(4)
Y(1)-C(1)
Y(1)-C(8)
Y(1)-H(0)
Y(1)-H(0′)
2.389(3)
2.343(3)
2.327((3)
2.365(3)
2.752(4)
2.738(4)
2.11(3)
Y(2)-N(5)
Y(2)-N(6)
Y(2)-N(7)
Y(2)-N(8)
Y(2)-C(27)
Y(2)-C(34)
Y(2)-H(0)
Y(2)-H(0′)
2.360(3)
2.327(3)
2.347(3)
2.398(3)
2.736(4)
2.760(4)
2.19(3)
2.16(3)
2.17(3)
N(1)-C(1)
N(2)-C(1)
N(3)-C(8)
N(4)-C(8)
1.338(5)
1.329(5)
1.329(5)
1.333(5)
N(5)-C(27)
N(6)-C(27)
N(7)-C(34)
N(8)-C(34)
1.332(5)
1.336(5)
1.332(5)
1.340(5)
Angles (deg)
N(1)-Y(1)-N(2)
N(5)-Y(2)-N(6)
N(3)-Y(2)-N(4)
N(7)-Y(2)-N(8)
C(1)-Y(1)-C(8)
57.92(10) H(0)-Y(1)-H(0′)
58.33(10) H(0)-Y(2)-H(0′)
58.13(10) Y(1)-H(0)-Y(2)
69.0(12)
67.5(12)
111.9(15)
57.85(10) Y(1)-H(0′)-Y(2) 111.0(15)
126.80(13)
C(27)-Y(2)-C(34) 124.45(13)
The monomeric complex is best described as trigonal-
planar with the yttrium in the center, considering the
benzamidinate ligands to occupy one coordination vertex
(C(1)-Y(1)-C(15) ) 122.71(13)°; C(1)-Y(1)-C(29) )
119.23(14)°, C(15-Y(1)-C(29) ) 117.76(15)°; sum of the
angles, 359.7(2)°). With torsion angles of -2.2(2)°
(N(1)-Y(1)-N(2)-C(1)) and -1.4(2)° (N(3)-Y(1)-N(4)-
C(15)), both benzamidinate ligands form planar rings
with the yttrium atom.
The almost identical C-N distances in the benz-
amidinate ligands (C-Nav ) 1.337(6) Å, Table 2),
corresponding to a bond order of 1.5,29 indicate full
electron delocalization within the NCN fragment,
Meta l-Ca r bon Bon d Hyd r ogen olysis. Syn th esis
a n d Ch a r a cter iza tion of {[p-X-C6H4C(NSiMe3)2]2Y-
(µ-H)}2 (9, X ) H; 9OMe, X ) OMe). (a ) Syn th esis. In
contrast to the facile hydrogenolysis of Cp*2YCH-
(SiMe3)2,2b which is completed within hours at 0 °C,
hydrogenolysis of 8 is slow and can be best performed
in benzene under 4 bar of hydrogen at room temperature
(3 days), resulting in the formation of H2C(SiMe3)2 and
{[PhC(NSiMe3)2]2Y(µ-H)}2 (9, eq 1). This low rate may
whereas the rather short Y-N distances (Y-Nav
)
2.338(4) Å) suggest π-interaction of the ligands with
yttrium.27 The dihedral angles N(1)-C(1)-C(2)-C(3)
(69.6(6)°) and N(3)-C(15)-C(16)-C(17) (-85.3(5)°) and
the C(1)-C(2) (1.492(7) Å) and C(15)-C(16) (1.499(6)
Å) distances, which correspond to C(sp2)-C(sp2) single
bonds,29 exclude conjugation between the phenyl ring
and the NCN fragment. The Y(1)-C(29) σ-bond (2.431(5)
Å) is significantly shorter than in Cp*2YCH(SiMe3)2
(2.468(7) Å)27 and compares well with the Y-C σ-bond
in Cp*2YMe.THF (2.44(2) Å).24 The trigonal-planar
molecule is formed by three closely interlocking ligands
around yttrium to adopt a geometry with minimal steric
repulsions. The molecule appears in solution to be very
flexible since, instead of many resonances due to various
inequivalent SiMe3 groups with inequivalent methyl
be a consequence of a stronger Y-C σ-bond in 8,
combined with less effective charge stabilization in the
heterolytic transition state as a result of the lower
electron-donating capacity of the benzamidinate anion
compared to Cp* and the more ionic character of the
bis(benzamidinate) system.6c,8a,30 Another possibility is
that the driving force for hydrogenolysis is reduced due
to the lower stability of the initially formed monomeric
hydride, compared to Cp*2YH. Steric crowding as
reason for the low reaction rate is not realistic, since
two benzamidinate ligands are not likely to occupy more
space than two Cp* ligands (vide infra). The influence
of electronic properties of the ancillary ligand system
on the reactivity of a complex is clearly illustrated by
the fact that even under drastic conditions no hydro-
1
substituents, the H and 13C NMR spectra of 8OMe only
show one singlet resonance for the methyl groups of the
benzamidinates and one singlet for the bis(trimethyl-
silyl)methyl ligand. The rapid equilibration of the
various methyl substituents may result from an easy
cogwheel type rotation of the ligands around the respec-
tive Y-C axes (Y(1)-C(1), Y(1)-C(15), Y(1)-C(29)). The
bonding of the alkyl group (CH(SiMe3)2) also supports
the view that the configuration around the metal is
mainly determined by steric interactions among the
ligands. As observed for all crystallographically char-
acterized lanthanoid bis(trimethylsilyl)methyl com-
pounds, C(29) has an almost planar geometry (Si(5)-
C(29)-Si(6) ) 121.8(3)°, Y(1)-C(29)-Si(5) ) 115.6(2)°;
Y(1)-C(29)-Si(6) ) 116.1(2)°; sum of the angles,
(30) Nolan, S. P.; Stern, D.; Hedden, D.; Marks, T. J . In Bonding
Energetics in Organometallic Compounds; Marks, T. J ., Ed.; ACS
Symposium Series 248; American Chemical Society: Washington, DC,
1990.
(29) Burke-Laing, M.; Laing, M. Acta Crystallogr. 1976, 32B, 3216.

2284 Organometallics, Vol. 15, No. 9, 1996
Duchateau et al.
genolysis was observed for the sterically unsaturated
[OEP]LnCH(SiMe3)2 (Ln ) Y, Lu).8a
formation of the hydride 9 were investigated. Attempts
to prepare it through thermolysis of an in situ prepared
alkyl complex, [PhC(NSiMe3)2]2YR (R ) t-Bu, n-Bu),
treatment of the chloride 2 with NaH,36 and treatment
of the borohydride 3 with NR3, to abstract BH3‚NR3,37
all failed.
A related method also remained unsuccessful but gave
a very interesting view on the high lability of the
benzamidinate ligands. The reaction of 2 with LiAlH4
was expected to give [PhC(NSiMe3)2]2Y(AlH4) which, on
treatment with an amine should afford 9 and AlH3‚
NR3.23b Instead, ligand exchange took place resulting
in formation of the monomeric bis(N,N′-bis(trimethyl-
silyl)benzamidinato)aluminum hydride, [PhC(NSiMe3)2]2-
AlH (eq 2), confirming the high affinity of the strong
Lewis acid Al3+ for nitrogen donors.38
The hydride 9 is the first example of a fully charac-
terized cyclopentadienyl-free yttrium hydride. In con-
trast with the other bis(N,N′-bis(trimethylsilyl)benz-
amidinate complexes described above, it is sparingly
soluble in benzene and essentially insoluble in aliphatic
hydrocarbons. It is extremely oxygen and moisture
sensitive but thermally quite stable and shows no sign
of decomposition after several days at 100 °C in benzene-
d6. A remarkable observation made during the ther-
molysis study is that H/D scrambling or metalation of
benzene-d6, which is a very easy process for {Cp*2Ln-
(µ-H)}2 (Ln ) Sc, Y, lanthanides) systems,2b,c,f,25,31 was
not observed. This clearly reflects the different elec-
tronic situation in 9 when compared with {Cp*2Y(µ-H)2.
Probably, like the absence of agostic interactions and
the slow hydrogenolysis, the lack of H/D exchange can
be related as well to the increased ionic character of the
bis(benzamidinato)yttrium system.
Hydrogenolysis of [PhC(NSiMe3)2]2YCH2Ph.THF (7)
in benzene-d6 also gives 9, although the coordinated
THF retards the rate considerably. 1H NMR spectros-
copy showed that within 2 days at 50 °C, 44% of 7 had
been converted into 9. Remarkably, 9 shows no ten-
dency to form a THF adduct, while no indication for
ether splitting could be obtained either. In contrast,
{[C5H4Me]2Y(µ-H)‚THF}2 and {[1,3-C5H3Me2]2Y(µ-H)‚
THF}2, reported by Evans et al., were isolated as stable
THF adducts,32 whereas bis-Cp* yttrium and lanthanide
hydrides, {Cp*2Ln(µ-H)}2 (Ln ) Y, lanthanides), give
very fast C-O activation with ethers, yielding the
alkoxo or µ-oxo compounds.2f,25b,31 Independent NMR
tube experiments confirmed that 9 does not react with
THF (1-5 equiv) in benzene-d6. However, when dis-
solved in neat THF, C-O bond activation, similar as
found for {Cp*2Ce(µ-H)}2,31c,33 was observed. A more
extensive discussion of the stability and reactivity of 9
will be given elsewhere.34 Analogously, reaction of 8OMe
with hydrogen resulted in the formation of H2C(SiMe3)2
and the corresponding hydride {[p-MeO-C6H4C-
(NSiMe3)2]2Y(µ-H)}2 (9OMe).35
1
(b) Ch a r a cter iza tion . The H NMR spectrum of 9
1
displays a characteristic Y-H coupling (triplet, J Y-H
) 27.6 Hz), consistent with a (time-averaged) symmetric
dimeric structure in solution. The Y-H resonance (δ
8.28 ppm) is at extreme lowfield compared to other
yttrium hydrides (2.02-5.45 ppm), while the coupling
constant (27.6 Hz) is quite similar.6c,e,10b,25,32 As ob-
served for all complexes described in this paper, the
single resonance (1H, 13C NMR) for the SiMe3 groups
indicates fluxional benzamidinate ligands in 9 at room
temperature. From the coalescence temperature and
∆νc, the Gibbs energy for rotation of the benzamidinate
ligands around the yttrium center was calculated (∆Gq
Tc
) 48 ( 1 kJ ‚mol-1) and found to be intermediate to
those for 4 and 6. Assuming that the bonding mode of
the ancillary ligands is comparable in the complexes
examined, the differences in fluxionality (and ∆Gq
Tc
values) can be explained by the different steric crowding
in the complexes (vide supra) and suggests that the
steric bulk increases from 6 f 9 f 4.
Since the yield of 9 by hydrogenolysis of 8 appeared
to be quite variable, other synthetic strategies for the
The chemical shift and coupling constant for the
1
R-carbon resonance in 8OMe (dd, δ 42.9 ppm, J C-H
)
1
88 Hz, J Y-C ) 31 Hz) and the hydride resonance in
(31) (a) Evans, W. J .; Ulibarri, T. A.; Ziller, J . W. Organometallics
1991, 10, 134. (b) Deelman, B.-J . Ph.D. Thesis, University of Gronin-
gen, 1994. (c) Deelman, B.-J .; Booij, M.; Meetsma, A.; Teuben, J . H.;
Kooijman, H.; Spek, A. L. Organometallics 1995, 14, 2306.
(32) (a) Evans, W. J .; Meadows, J . H.; Wayda, A. L.; Hunter, W. E.;
Atwood, J . L. J . Am. Chem. Soc. 1982, 104, 2008. (b) Evans, W. J .;
Meadows, J . H.; Hunter, W. E.; Atwood, J . L. J . Am. Chem. Soc. 1984,
106, 1291. (c) Evans, W. J .; Drummond, D. K.; Hanusa, T. P.; Doedens,
R. J . Organometallics 1987, 6, 2279. (d) Evans, W. J .; Sollberger, M.
S.; Khan, S. I.; Bau, R. J . Am. Chem. Soc. 1988, 110, 439.
(33) The quantitative formation of ethane (To¨pler pomp determi-
nation), together with olefinic resonances in the 1H NMR of the product
mixture, suggests the formation of an enolate [Y]-OCHdCH2 species.
Minor amounts of ethylene formed suggest a second C-O activation
reaction of the enolate species, probably forming a µ-oxo species: ref
31b,c.
1
9OMe (t, δ 8.31 ppm, J Y-H ) 27.8 Hz) are almost
1
identical to those found for 8 (dd, δ 43.5 ppm, J C-H
)
)
1
1
88 Hz, J Y-C ) 30 Hz) and 9 (t, δ 8.28 ppm, J Y-H
27.6 Hz). It is clear that the electronic influence of the
para-methoxy substituent of the benzamidinate ligands
in 8OMe and 9OMe is negligible like earlier assumed on
the fact that the aryl group is almost perpendicular to
the NCN plane.
The molecular structure of 9 was determined by a low-
temperature X-ray diffraction analysis. An ORTEP
drawing of 9 is shown in Figure 3, and selected bond
(34) Duchateau, R.; van Wee, C. T.; Teuben, J . H. Organometallics
1996, 15, 2291.
(36) (a) Schumann, H.; Genthe, W. J . Organomet. Chem. 1981, 213,
C7. (b) Schumann, H.; Genthe, W.; Hahn, E.; Hossain, M. B.; van der
Helm, D. J . Organomet. Chem. 1986, 299, 67. (c) Qian, C.; Deng, D.;
Ni, C.; Zhang, Z. Inorg. Chim. Acta 1988, 146, 129.
(37) J ames, B. D.; Nanda, R. K.; Wallbridge, M. G. H. Inorg. Chem.
1967, 6, 1979.
(38) The characterization, determination of the X-ray crystal struc-
ture, and reactivity of the aluminum hydride [PhC(NSiMe3)2]2AlH is
beyond the scope of this paper and will be reported elsewhere.
Duchateau, R.; Meetsma, A.; Teuben, J . H. J . Chem. Soc., Chem.
Commun., submitted for publication.
(35) An important observation is the lack of reactivity of the hydride
toward the p-anisyl functionality within 9OMe. Like alkyllithium
reagents, {Cp*2Y(µ-H)}2 is well-known for its facile ortho-metalation
reactions with heteroatom-containing arenes, PhX (X ) OMe, SMe,
NMe2, CH2NMe2, PMe2). For instance, the reaction of {Cp*2Y(µ-H)}2
with anisole is instantaneous at room temperature, yielding
Cp*2Y(η2-(C,O)-C6H4-2-OMe): (a) Reference 25. (b) Beak, P.; Snieckus,
V. Acc. Chem. Res. 1982, 15, 306 and references cited therein. (c)
Brandsma, L.; Verkruysse, H. Preparative Polar Organometallic
Chemistry; Springer-Verlag: Berlin, 1987; Vol. 1.

Bis(benzamidinato)yttrium Compounds
Organometallics, Vol. 15, No. 9, 1996 2285
F igu r e 4. CPK models of Cp2Y (A), [PhC(NSiMe3)2]2Y (B),
and Cp*2Y (C) in two different orientations.
of the ancillary ligands as well as the charge distribution
within the Y-R bond will influence the stability and
reactivity of the compounds. Therefore, an attempt to
compare the effects of the steric bulk and electronic
structure of systems containing benzamidinate and
(pentamethyl)cyclopentadienyl ligands was made using
simple and commercially available computing facilities.
(a ) Ster ic P r op er ties. In 1970, Tolman quantified
the steric effects observed in organometallic systems in
F igu r e 3. ORTEP drawing of the molecular structure of
{[PhC(NSiMe3)2]2Y(µ-H)}2 (9). Hydrogen atoms on the
benzamidinate ligands are omitted for clarity.
distances and angles are listed in Table 2. Details
concerning the data collection are listed in Table 5.
The molecule is a dimer formed by two edge-sharing
severely distorted octahedral yttrium fragments, each
coordinated by two chelating benzamidinate ligands.
Two bridging hydrogen atoms form the shared edge. The
structure is very similar to the closely related {[PhC-
(NSiMe3)2]2Y(µ-CtCH)}2, reported earlier,39 and like
there, the axial bonds Y(1)-N(1) (2.389(3) Å) and Y(1)-
N(4) (2.365(3) Å) are longer than the equatorial Y(1)-
N(2) (2.343(3) Å) and Y(1)-N(3) (2.327(3) Å) bonds. With
N(1)-Y(1)-N(2) and N(3)-Y(1)-N(4) bond angles of
57.92(10) and 58.13(10)°, the bite angles of the benz-
amidinate ligands are very similar to those in {[PhC-
(NSiMe3)2]2Y(µ-CtCH)}2 (57.92(13) and 58.12(13)°)39
and in 8OMe (58.85(12), 58.50(12)°). The larger N(1)-
Y(1)-N(4) (160.94(10)°) and N(2)-Y(1)-N(3) (102.51(10)°)
angles and smaller H(0)-Y(1)-H(0′) angle (69.0(12)°)
compared with the corresponding angles in {[PhC-
(NSiMe3)2]2Y(µ-CtCH)}2 (N(5)-Y(3)-N(8) ) 149.33(15)°;
N(6)-Y(3)-N(7) ) 98.70(14)°; C(29)-Y(3)-C(29a) )
78.83(15)°)39 show that the yttrium centers in 9 tend to
adopt prism geometry. With equal N-C distances
within the benzamidinate ligands (see Table 2), it is
clear that the π-electrons within the NCN fragments
are delocalized, just like in 8OMe and {[PhC(NSiMe3)2]2Y-
(µ-CtCH)}2. The hydride bridges are symmetrical in
the crystal structure (with identical Y(1)-H(0) (2.11(3)
Å) and Y(1)-H(0)′ (2.16(3) Å), and they appear to
remain so in solution, judging from the triplet signal
terms of cone angles.40
Due to its simplicity and
usefulness, this method has become widely used for
quantifying ligand sizes. While mostly applied to
determine the steric bulk of phosphine and phosphido
ligands, the cone angle concept has also been used for
other ligands including cyclopentadienyls.41 Two im-
portant limitations of Tolman’s approach that have to
be considered are that (i) conical geometry of the metal-
ligand fragment is assumed and (ii) other ligands
around the metal are ignored. This makes the method
rather inaccurate when comparing the steric bulk of
geometrically different ligands, such as dish-shaped
cyclopentadienyl and rectangular benzamidinate ligands.
Furthermore, when one is dealing with systems con-
taining more than one of these ligands, the “effective
steric bulk” of the ligand system is dramatically influ-
enced by the way the ligands are oriented around the
metal. Therefore, differences in steric bulk of ancillary
ligand systems are described more accurately in terms
of openness of the metal coordination gap, rather than
comparing the difference in cone angle of the individual
ligands. Brintzinger et al.42
used this method to deter-
mine the differences in steric bulk of various metallo-
cene systems (vide infra). As a measure for the open-
ness of metallocenes, they introduced the term coordi-
nation aperture, defined by the angle between the two
planes through the metal center that touch the inner
van der Waals surface of the ligand system.
1
for the hydrido resonances in the H NMR spectrum of
9 (vide supra). The Y-H distances and Y-H-Y angles
are very similar compared to values found for {[C5H4-
On the basis of the cone angle of Cp (136°) and PhC-
(NSiMe3)2 (137°), Edelmann et al. estimated that the
bis(N,N′-bis(trimethylsilyl)benzamidinate) system is ster-
ically equivalent to the bis(cyclopentadienyl) ligand
environment.17b It is not clear whether the limitations
of the cone angle approach were taken into consider-
ation. Since steric effects have normally a large influ-
32a
Me]2Y(µ-H)‚THF}2 and {[1,3-Me2C5H3]Y(µ-H)‚THF}2.32c
Assessin g th e Ster ic a n d Electr on ic F a ctor s th a t
Deter m in e th e Differ en ce betw een th e Bis(N,N′-
bis(tr im eth ylsilyl)ben za m id in a te) a n d Bis(p en ta -
m eth ylcyclop en ta d ien yl) Liga n d System s. Differ-
ences in both steric bulk and electron-donating capacity
(40) (a) Tolman, C. A. J . Am. Chem. Soc. 1970, 92, 2956. (b) Tolman,
C. A. Chem. Rev. 1977, 77, 313.
(39) Duchateau, R.; van Wee, C. T.; Meetsma, A.; Teuben, J . H. J .
Am. Chem. Soc. 1993, 115, 4931.
(41) White, D.; Civille, N. J . Adv. Organomet. Chem. 1994, 36, 95.
(42) Hortmann, K.; Brintzinger, H. H. New J . Chem. 1992, 16, 51.

2286 Organometallics, Vol. 15, No. 9, 1996
Duchateau et al.
Ta ble 3. AO Con tr ibu tion s (Squ a r es) in Loca lized
Liga n d -Meta l Bon d in g MO’s of [HC(NH)2]2YCH3
(contr)2 of Y
(contr)2 of ligand
dyz
0.06
N3, N4
px
s
pz
py
0.28
0.27
0.16
0.08
px
0.07
N1, N2
px
s
pz
py
0.32
0.27
0.13
0.08
F igu r e 5. Perspective view of the [HC(NH)2]2YCH3 and
[C5H5]2YCH3 models used in INDO/1 calculations.
The models [HC(NH)2]2YCH3 and [C5H5]2YCH3 used for
the INDO/1 calculations are presented in Figure 5.45 The
significant ligand to metal bonding interactions in
[HC(NH)2]2YCH3 are listed in Table 3.
ence on the reactivity, the steric bulk of the various
ligand systems were compared using space-filling mod-
els and Brintzinger’s approach.
Figure 4 shows CPK models of the Cp2Y (A), [PhC-
(NSiMe3)2]2Y (B), and Cp*2Y (C) fragments, respec-
tively.43 Although not leading to quantitative results,
the space-filling models give an interesting picture of
the relative geometric differences of the ligand systems.
The bis(cyclopentadienyl) system is definitely the small-
est, whereas the bis(pentamethylcyclopentadienyl) ligand
environment is sterically the most demanding. On the
basis of the CPK models (Figure 4), it is clear that the
size of the free coordination space left by the bis(N,N′-
bis(trimethylsilyl)benzamidinate) ligand environment is
considerably smaller than that of the bis(cyclopenta-
dienyl) ligand set and resembles more that of the bis-
(pentamethylcyclopentadienyl) system. For the ligand
systems depicted in Figure 4, the coordination apertures
were determined as well. With an angle of 103°, for
Cp2Y the coordination gap is by far the largest. The
assumption made above, that the steric bulk of [PhC-
(NSiMe3)2]2Y (84°) resembles more that of Cp*2Y (72°)
than that of Cp2Y, is supported by their coordination
apertures. Clearly, this outcome differs considerably
from the conclusions reached by Edelmann et al. who
postulated that benzamidinate ligands are sterically
equivalent with Cp.17b
For [HC(NH)2]2YCH3 each nitrogen is bonded to the
metal by one σ-orbital. The orbitals (mainly px + s +
pz) of the two equatorial nitrogens overlap with yttrium-
dyz, whereas the orbitals (mainly px + s) of the axial
nitrogens overlap with yttrium-px. With bond orders
of 0.74 (Y1-N1, Y1-N2) and 0.78 (Y1-N3, Y1-N4) the
Y-N bonds are almost identical. Additional π-interac-
tion of the HC(NH)2 ligands with yttrium could not be
observed and can therefore be assumed to be negli-
gible.47 Hence, benzamidinate ligands can formally be
regarded as four electron donors.
The Y-C σ-bond is very similar in both systems
(Table 4). The carbon contribution is mainly pz, whereas
2
the yttrium contribution consists of dz + pz + s. The
bond orders and calculated bond dissociation enthalpies
are identical. Only the Mulliken charge distributions
are significantly different. Although using a Mulliken
population analysis to determine the polarity of the Y-C
bond should be met with reservation, it will be assumed
that, because of the fact that the differences are quite
large, the results obtained for the two ligand systems
under consideration reflect real bonding situation.
Whereas the charge at the CH3 group remains more or
less the same in both complexes, the formal yttrium
charge in these systems differs significantly. Clearly,
the yttrium centers in [HC(NH)2]2YCH3 (q(Y) ) +0.80
e) is considerably more positive than in [C5H5]2YCH3
(q(Y) ) +0.48 e). Consequently, the charge separation
within the Y-C bond in [HC(NH)2]2YCH3 (∆q(Y-C) )
1.06 e) is larger than in [C5H5]2YCH3 (∆q(Y-C) ) 0.73
e). Hence, Y-C in [C5H5]2YCH3 can be considered to
be less polar than in the former system. It is not only
the Y-C bonds in [HC(NH)2]2YCH3 which seem to be
more polar; the electron density at the HC(NH)2 (q(L)
) -0.27 e) is also higher than that at C5H5 (q(L) )
-0.12 e), making [HC(NH)2]2YCH3 more ionic than
[C5H5]2YCH3. The larger negative charge at the benz-
amidinate ligands probably originates from the high
electronegativity of nitrogen. As a consequence of the
high positive charge of the metal in bis(benzamidinato)-
yttrium complexes, the yttrium orbitals are strongly
contracted on the metal, thus hampering initial interac-
tions with substrates or C-H/C-Si bond electron pairs
(b) Electr on ic P r op er ties. To compare the elec-
tronic structure of bis(N,N′-bis(trimethylsilyl)benz-
amidinato)- and bis(pentamethylcyclopentadienyl)yttrium
systems, simple qualitative INDO/1 semi-empirical MO
calculations, as implemented in the program ZINDO,44
have been performed. To simplify the calculations,
stripped and symmetrized model molecules were used:
[HC(NH)2]2YCH3 with local C2 symmetry and [C5H5]2-
YCH3 with local C2v symmetry.45 For the fragments,
•
CH3 , [C5H5]2Y•, and [HC(NH)2]2Y•, ROHF calculations
were carried out, whereas for the complete systems,
[C5H5]2YCH3 and [HC(NH)2]2YCH3, RHF calculations
were performed in order to get an estimate of the Y-Cσ
bond strength. No geometry optimalizations were per-
formed. The bonding of cyclopentadienyl ligands to
metal centers has extensively been studied by others
and will not be further discussed.46 To simplify the
interpretation of the results, the orbitals were localized.
(43) X-ray crystal data were used from the following. {Cp2Y(µ-
Me)}2: Holton, J .; Lappert, M. F.; Ballard, D. G. H.; Pearce, R.; Atwood,
J . L.; Hunter, W. E. J . Chem. Soc., Dalton Trans. 1979, 54; {[PhC-
(NSiMe3)2]2Y(µ-H)}2 (9), Cp*2YCH(SiMe3)2: Reference 27. CPK models
were prepared using PLUTON-92: Spek, A. L. PLUTON-92; University
of Utrecht: Utrecht, The Netherlands, 1992.
(44) Zerner, M. C. ZINDO, a comprehensive semi-empirical quantum
chemistry package; University of Florida: Gainesville, FL.
(45) For details, see the Experimental Section.
(46) Deelman, B.-J .; Teuben, J . H.; MacGregor, S. A.; Eisenstein,
O. New. J . Chem. 1995, 19, 691 and references cited therein.
(47) INDO/1 ROHF calculations on [HC(NH)2]• showed that the N
and C π-orbitals are involved in π-bonding within the ligand, resulting
in complete charge delocalization within the NCN fragment of the
benzamidinate ligand.

Bis(benzamidinato)yttrium Compounds
Organometallics, Vol. 15, No. 9, 1996 2287
Ta ble 4. Y-C σ-Bon d : AO Con tr ibu tion s (Squ a r es), Bon d Or d er s (b.o.), Mu llik en F or m a l Ch a r ges (q), a n d
Ca lcu la ted Bon d Dissocia tion En th a lp ies
(contr)2 of C
0.459
(contr)2 of Y
complex
b.o.
q(CH3)
q(Y)
∆q(Y-C)
q(L)
Ecalcd
2
2
[C5H5]2YCH3
pz
s
dz
pz
s
dz
pz
s
0.142
1.03
-0.25
+0.48
0.73
-0.12
120
0.149
0.138
0.108
0.144
0.118
0.116
[HC(NH)2]2YCH3
pz
s
0.471
0.148
1.03
-0.26
+0.80
1.06
-0.27
120
48
prepared by continuous extraction of anhydrous YCl3 with
THF. [PhC(NSiMe3)2]Li49 and [p-MeOC6H4C(NSiMe3)2]Li49b,50
were prepared according to literature procedures. NMR
spectra were recorded on a Varian VXR 300 (1H NMR at 300
MHz, 13C NMR at 75.4 MHz, 89Y NMR at 14.697 MHz)
and causing low hydrogenolysis rates and lack of H/D
exchange and agostic interactions.
Con clu sion s
spectrometer. The H and 13C NMR spectra, measured at 30
1
It is clear that benzamidinate ligands can effectively
stabilize Y-X (X ) heteroatom, C, H) bonds, and in this
respect they form robust alternatives for (pentamethyl)-
cyclopentadienyl ligands. The bis(benzamidinate) ligand
system has a very pronounced shape, quite different
from the bis(pentamethylcyclopentadienyl) ligand set as
follows from X-ray structure determinations. It appears
that in solution the bis(benzamidinate) system is very
flexible (∆GqTc(rotation) ) 39-57 kJ ‚mol-1) giving freely
rotating nonrigid structures at room temperature. The
complexes described show a strong similarity with their
bis(pentamethylcyclopentadienyl)yttrium analogs: [PhC-
(NSiMe3)2]2YCl‚THF (2) readily undergoes salt metath-
esis reactions to form new Y-X and Y-C bonds.
Hydrogenolysis of the alkyl complexes [PhC(NSiMe3)2]2-
YR (R ) CH2Ph.THF (7), CH(SiMe3)2 (8)) leads to the
hydride {[PhC(NSiMe3)2]2Y(µ-H)}2 (9). The thermal
stability of all complexes is high, showing no dispropor-
tionation or ligand transfer at elevated temperatures,
and even the steric bulk of the bis(benzamidinate)
coordination is comparable with that of the bis(penta-
methylcyclopentadienyl) ligand set. However, several
important differences were observed as well. One
outstanding aspect of the new ancillary ligand system
is that the benzamidinates are transferred more easily
than Cp or Cp* ligands. This is demonstrated in the
reaction of 2 with LiAlH4, where both benzamidinate
ligands are transferred from yttrium to aluminum. The
main difference between both groups of compounds
arises from the higher ionicity of the bis(benzamidinate)
system. The larger negative charge on the ancillary
ligand system leads to a more positively charged yttrium
atom. As a result, the yttrium orbitals are more
contracted on the metal, which possibly causes the lower
tendency of the yttrium atom to engage in agostic
interactions and activation or precomplexation of sub-
strates (e.g. H2) leading to the low hydrogenolysis rate
and lack of H/D exchange.
°C, were referenced internally using the residual solvent
resonances. 89Y NMR spectra were measured at 25 °C using
10 mm sample tubes containing 2.5 mL of 4.5-5.5 M solutions
in benzene-d6. Because of the negative nuclear Overhauser
effect of 89Y, the decoupler was not used. The very long
relaxation times commonly observed for 89Y made it necessary
to use delays between π/2 pulses of 300 s. Obtaining data was
further hindered by acoustic ringing (seen as a rolling base-
line). Chemical shifts are reported with respect to a 2.0 M
sample of YCl3 in D2O (δ ) 0 ppm). To achieve a signal-to-
noise ratio of at least 30, 100-300 transients were ac-
cumulated. IR spectra were recorded on a Mattson-4020
Galaxy FT-IR spectrophotometer. Elemental analyses were
carried out at the Analytical Department of this laboratory;
quoted data are the average of at least two independent
determinations.
P r ep a r a tion of [P h C(NSiMe3)2]2Y(µ-Cl)2Li‚2THF (1).
[PhC(NSiMe3)2]Li (95.6 mL, 1.0 M solution in pentane, 95.6
mmol) was added to a suspension of YCl3‚3.5THF (21.4 g , 47.8
mmol) in THF (300 mL) at -30 °C. The mixture was warmed
to room temperature and stirred for 24 h after which time the
solvent was evaporated and the compound dried thoroughly.
Extraction with ether (200 mL) and subsequent concentration
and cooling to -30 °C yielded 1 (27.7 g, 33.0 mmol, 69%) as a
colorless microcrystalline material. 1H NMR (benzene-d6, δ):
7.22 (m, 4H, Ar), 7.05 (m, 6H, Ar), 3.90 (s, 4H, THF-R-CH2),
1.43 (s, 4H, THF-â-CH2), 0.14 (s, 36H, PhC[NSi(CH3)3]2).
13C{1H} NMR (benzene-d6, δ): 183.9 (s, PhC[NSiMe3]2), 143.8
(s, Ar), 128.1 (s, Ar), 126.3 (s, Ar), 70.2 (s, THF-R-CH2), 25.5
(s, THF-â-CH2), 2.5 (s, PhC[NSi(CH3)3]2). The crystalline
product appeared to gradually loose THF. Therefore no
satisfactory elemental analysis could be obtained.
P r epar ation of [P h C(NSiMe3)2]2YCl‚THF‚0.25(pen tan e)
(2). Meth od a . [PhC(NSiMe3)2]Li (190 mL, 1.0 M solution
in pentane, 0.19 mol) was added to a suspension of YCl3‚3.5THF
(43 g, 96 mmol) in THF (200 mL) at -30 °C. The mixture
was warmed to room temperature and stirred for 24 h after
which time the solvent was evaporated and the compound
dried thoroughly. The residue was subsequently refluxed with
pentane (400 mL) to cause the LiCl to separate out. The
solvent was evaporated again under vacuum, and the residue
was transferred to a Schlenk tube equipped with a frit and
continuously extracted with pentane. The pentane solution
then was concentrated until crystallization started. Cooling
to -30 °C yielded 2 (52.0 g, 70.1 mmol, 73%) as colorless
crystals. Meth od b. A suspension of 1 (5.3 g, 6.3 mmol) in
pentane (80 mL) was refluxed for 2 h. Then the volatiles were
pumped off in vacuo, and the product was extracted with
pentane (100 mL). Concentration and cooling to -30 °C
Exp er im en ta l Section
Gen er a l Com m en ts. All compounds are extremely oxygen
and moisture sensitive. Manipulations were carried out under
nitrogen using glovebox (Braun MB-200) and Schlenk tech-
niques. Hydrogen (Hoek-Loos 99.9995%) was used as pur-
chased. Solvents were distilled from Na (toluene), K (THF),
or Na/K alloy (ether, pentane, hexane, benzene) and stored
under nitrogen. Benzene-d6 was dried over Na/K alloy and
distilled prior to use. LiAlH4 (Aldrich) was suspended in THF,
yielding a 1.75 M solution after filtration. YCl3‚3.5THF was
(48) Freeman, J . H.; Smith, M. L. J . Inorg. Nucl. Chem. 1958, 7,
224.
(49) (a) Sanger, A. R. Inorg. Nucl. Chem. Lett. 1973, 9, 351. (b) Boere´,
R. T.; Oakley, R. T.; Reed, R. W. J . Organomet. Chem. 1987, 331, 161.
(50) Wedler, M.; Kno¨sel, F.; Noltemeyer, M.; Edelmann, F. T.;
Behrens, U. J . Organomet. Chem. 1990, 388, 21.

2288 Organometallics, Vol. 15, No. 9, 1996
Duchateau et al.
1
yielded 2 (4.1 g, 5.5 mmol, 87%) as colorless needles. IR (KBr/
Nujol, cm-1): 2951 (vs), 2857 (s), 1601 (w), 1578 (w), 1447 (s),
1412 (vs), 1343 (sh), 1316 (m), 1294 (m), 1248 (s), 1169 (m),
1074 (m), 1030 (m), 1009 (s), 986 (vs), 922 (m), 839 (vs), 791
(s), 758 (vs), 725 (s), 704 (s), 685 (s), 604 (m), 482 (s), 440 (m).
1H NMR (benzene-d6, δ): 7.12 (m, 10H, Ar), 4.20 (s, 4H, THF-
R-CH2), 1.55 (s, 4H, THF-â-CH2), 1.23 (m, 1.5H, pentane), 0.88
(m, 1.5H, pentane), 0.13 (s, 36H, PhC[NSi(CH3)3]2). 13C{1H}
NMR (benzene-d6, δ): 183.9 (s, PhC[NSiMe3]2), 143.5 (s, Ar),
128.1 (s, Ar), 126.2 (s, Ar), 71.8 (s, THF-R-CH2), 25.3 (s, THF-
â-CH2), 22.7 (s, pentane), 14.2 (s, pentane), 2.5 (s, PhC[NSi-
(CH3)3]2). 89Y NMR (benzene-d6, δ): 426. Anal. Calcd (found)
for C30H54ClN4OSi4Y‚0.25C5H12): C, 50.62 (50.49); H, 7.75
(7.75); Cl, 4.90 (4.80); Y, 11.99 (12.11).
1J C-H ) 152 Hz), 4.6 (q, N(Si(CH3)3)2, J C-H ) 116 Hz), 2.8 (q,
1
PhC[NSi(CH3)3]2, J C-H ) 118 Hz). Anal. Calcd (found) for
32H64N5Si6Y: C, 49.51 (48.99); H, 8.31 (8.32); Y, 11.45 (11.06).
C
P r ep a r a t ion of [P h C(NSiMe3)2]2YOAr (OAr ) 2,6-
(CMe3)2-4-MeC6H2) (5). ArOLi‚OEt2 (1.25 g, 4.2 mmol) was
added to a solution of 2 (3.1 g, 4.2 mmol) in toluene (40 mL)
at room temperature. After the solution was stirred for 14 h,
the solvent was pumped off and the residue was extracted with
pentane (50 mL). Concentration and slow cooling to -30 °C
yielded 5 (3.4 g, 4.1 mmol, 97%) as large colorless crystals. IR
(KBr/Nujol, cm-1): 2940 (vs), 2851 (vs), 2726 (m), 2672 (m),
1464 (vs), 1439 (s), 1377 (vs), 1262 (s), 1248 (s), 1155 (m), 1121
(w), 986 (w), 934 (w), 916 (m), 845 (s), 760 (m), 721 (m), 700
(w), 660 (w). 1H NMR (benzene-d6, δ): 7.21 (m, 6H, Ar), 7.02
(m, 6H, Ar), 2.35 (s, 3H, CH3), 1.75 (s, 18H, C(CH3)3), 0.03 (s,
36H, PhC[NSi(CH3)3]2). 13C NMR (benzene-d6, δ): 184.2 (s,
PhC[NSi(CH3)3]2), 159.9 (s, Ar), 142.5 (s, Ar), 137.0 (s, Ar),
P r epar ation of [p-MeOC6H4C(NSiMe3)2]2YCl‚THF (2OMe).
Analogous to the preparation of 2, this compound was obtained
from YCl3‚3.5THF (8.3 g, 18.5 mmol) and 2 equiv (10.9 g, 37.9
mmol) of [p-MeOC6H4C(NSiMe3)2]Li‚OEt2 in THF (110 mL).
After crystallization from pentane (50 mL) [p-MeOC6H4C-
(NSiMe3)2]2YCl‚THF (2OMe) was isolated as a colorless micro-
crystalline material (10.1 g, 13.0 mmol, 70%). IR (KBr/Nujol,
cm-1): 2936 (vs), 2837 (s), 1609 (s), 1576 (w), 1512 (s), 1452
(vs), 1416 (vs), 1379 (vs), 1292 (s), 1246 (s), 1171 (s), 1121 (w),
1197 (m), 1067 (w), 1038 (m), 1015 (m), 1001 (m), 986 (s), 939
(w), 843 (vs), 837 (vs), 758 (s), 745 (s), 727 (s), 683 (w), 644
(m), 629 (m), 604 (w), 529 (w), 500 (m), 426 (m). 1H NMR
1
2
128.8 (dt, Ar, J C-H ) 160 Hz, J C-H ) 7 Hz), 128.1 (d, Ar,
1J C-H ) 160 Hz), 126.6 (d, Ar, J C-H ) 154 Hz), 126.1 (d, Ar,
1
1J C-H ) 143 Hz), 124.7 (q, Ar, 2J C-H ) 6 Hz), 34.8 (s, C(CH3)3),
1
1
32.6 (q, C(CH3)3, J C-H ) 124 Hz), 21.6 (q, CH3, J C-H ) 124
Hz), 2.7 (q, PhC[NSi(CH3)3]2, J C-H ) 119 Hz). 89Y NMR
1
(benzene-d6, δ): 412. Anal. Calcd (found) for C41H69N4-
OSi4Y: C, 58.89 (58.84); H, 8.44 (8.55); Y, 10.63 (10.67).
P r ep a r a tion of [P h C(NSiMe3)2]2Y(µ-Me)2Li‚TMEDA (6).
An ethereal (50 mL) solution of 2 (3.0 g, 4.0 mmol) was cooled
to -80 °C and treated with MeLi (6.7 mL, 8.0 mmol). Upon
warming of the solution to room temperature, salt precipitated.
After addition of TMEDA (1.2 mL, 8.0 mmol), the volatiles
were removed in vacuo and the residue was extracted with
pentane (50 mL). Cooling to -30 °C yielded 6 (2.5 g, 3.3 mmol,
82%) as large colorless crystals. IR (KBr/Nujol, cm-1): 3100
(m), 3246 (w), 3079 (s), 2930 (vs), 2857 (vs), 2795 (s), 1508 (m),
1495 (s), 1458 (vs), 1377 (vs), 1358 (s), 1292 (s), 1240 (vs), 1181
(w), 1159 (w), 1130 (w), 1098 (w), 1071 (m), 1003 (s), 993 (s),
951 (m), 934 (w), 918 (m), 845 (vs), 833 (vs), 785 (s), 758 (s),
700 (s), 689 (m), 677 (s), 604 (m), 475 (s), 440 (m), 403 (m). 1H
NMR (benzene-d6, δ): 7.32 (m, 4H, Ar), 7.05 (m, 6H, Ar), 2.04
(s, 12H, TMEDA-CH3), 1.67 (s, 4H, TMEDA-CH2), 0.21 (s, 36H,
PhC[NSi(CH3)3]2), -0.48 (s, 6H, CH3). 13C NMR (benzene-d6,
δ): 182.7 (s, PhC[NSi(CH3)3]2), 144.2 (s, Ar), 127.8 (dd, Ar,
3
(benzene-d6, δ): 7.15 (d, 4H, Ar, J H-H ) 6.0 Hz), 6.67 (d, 4H,
3
Ar, J H-H ) 6.8 Hz), 3.87 (s, 4H, THF-R-CH2), 3.22 (s, 6H,
OCH3), 1.40 (s, 4H, THF-â-CH2), 0.17 (s, 36H, PhC[NSi-
(CH3)3]2). 13C NMR (benzene-d6, δ): 183.7 (s, PhC[NSiMe3]2),
159.8 (s, Ar), 136.0 (s, Ar), 127.6 (dd, Ar, 1J C-H ) 159 Hz, 2J C-H
) 7 Hz), 113.4 (dd, Ar, 1J C-H ) 160 Hz, 2J C-H ) 3 Hz), 69.8 (t,
THF-R-CH2, 1J CsH ) 148 Hz), 54.6 (q, OCH3, 1J C-H ) 144 Hz),
25.4 (t, THF-â-CH2, 1J C-H ) 133 Hz), 2.50 (q, PhC[NSi(CH3)3]2,
1J C-H ) 118 Hz). Anal. Calcd (found) for C32H58ClN4O3Si4Y:
C, 49.05 (48.67); H, 7.40 (7.46).
P r ep a r a tion of [P h C(NSiMe3)2]2YBH4‚THF (3). LiBH4
(0.8 g, 36.7 mmol) was added to a solution of 2 (2.5 g, 3.4 mmol)
in toluene (100 mL) at room temperature. After the mixture
was stirred for 14 h, the toluene was removed in vacuo and
the white residue was extracted with pentane (100 mL).
Repeated recrystallization from pentane (50 mL), concentra-
tion, and cooling to -30 °C yielded colorless crystals of 3 (1.9
g, 2.7 mmol, 79%). IR (KBr/Nujol, cm-1): 2955 (vs), 2926 (vs),
2872 (s), 2855 (s), 2448 (m), 2220 (w), 2170 (w), 1445 (s), 1439
(s), 1433 (vs), 1427 (vs), 1408 (s), 1246 (s), 1182 (w), 1009 (m),
986 (s), 918 (w), 839 (vs), 787 (m), 760 (s), 731 (m), 702 (m),
683 (m). 1H NMR (benzene-d6, δ): 7.18 (m, 4H, Ar), 7.04 (m,
6H, Ar), 4.06 (m, 4H, THF-R-CH2), 1.40 (m, 4H, THF-â-CH2),
1J C-H ) 159 Hz, J C-H ) 7 Hz), 127.4 (dt, Ar, J C-H ) 155 Hz,
2
1
2J C-H ) 7 Hz), 126.7 (dt, Ar, J C-H ) 160 Hz, J C-H ) 7 Hz),
1
2
1
56.9 (q, TMEDA-CH3, J C-H ) 134 Hz), 46.3 (t, TMEDA-CH2,
1J C-H ) 134 Hz), 10.1 (q, CH3, J C-H ) 116 Hz), 3.1 (q, PhC-
1
1
[NSi(CH3)3]2, J C-H ) 118 Hz). Anal. Calcd (found) for
C34H68LiN6Si4Y: C, 53.09 (53.19); H, 8.91 (8.89); N, 10.93
(10.94); Y, 11.56 (11.74).
1
P r ep a r a tion of [P h C(NSiMe3)2]2YCH2P h .THF (7). At
-80 °C, a solution of 2 (3.6 g, 4.9 mmol) in toluene (45 mL)
was treated with KCH2Ph (0.65 g, 5.0 mmol). The suspension
was allowed to warm to room temperature and then stirred
until all the KCH2Ph had reacted. The volatiles were pumped
off, and after being dried thoroughly, the residue was extracted
with pentane (50 mL). Concentration and cooling gave 7 as
an oily product. Repeated recrystallization from pentane (30
mL) and slow cooling to -30 °C yielded 7 (2.2 g, 2.8 mmol,
58%) as block-shaped pale yellow crystals. IR (KBr/Nujol,
cm-1): 3061 (w), 2926 (vs), 2857 (vs), 1589 (m), 1483 (m), 1447
(vs), 1429 (vs), 1398 (s), 1316 (w), 1296 (w), 1244 (s), 1215 (m),
1007 (m), 984 (s), 914 (m), 899 (m), 845 (s), 797 (m), 785 (m),
758 (s), 735 (m), 698 (m), 683 (m), 482 (m). 1H NMR (benzene-
d6, δ): 7.15 (m, 15H, Ar), 3.91 (s, 4H, THF-R-CH2), 2.25 (d,
1.32 (q, 4H, BH4, J B-H ) 80 Hz), 0.10 (s, 36H, PhC[NSi-
(CH3)3]2). 13C NMR (benzene-d6, δ): 182.9 (s, PhC[NSiMe3]2),
143.0 (s, Ar), 128.4 (d, Ar, 1J C-H ) 164 Hz), 128.0 (d, Ar, 1J C-H
1
) 163 Hz), 126.1 (d, Ar, J C-H ) 133 Hz), 72.3 (t, THF-R-CH2,
1
1J C-H ) 129 Hz), 25.2 (t, THF-â-CH2, J C-H ) 129 Hz), 2.5 (q,
1
PhC[NSi(CH3)3]2, J C-H ) 118 Hz). Anal. Calcd (found) for
C
30H58BN4OSi4Y: C, 51.26 (50.98); H, 8.32 (8.40); Y, 12.65
(12.93).
P r ep a r a tion of [P h C(NSiMe3)2]2YN(SiMe3)2 (4). A solu-
tion of 2 (2.6 g, 3.5 mmol) in toluene (75 mL) was treated with
NaN(SiMe3)2 (0.64 g, 3.5 mmol) at room temperature and
stirred overnight. Then the volatiles were removed in vacuo
and the residue extracted with pentane (75 mL). Concentra-
tion and cooling to -30 °C yielded 4 (2.1 g, 2.7 mmol, 77%) as
a colorless microcrystalline solid. IR (KBr/Nujol, cm-1): 2932
(vs), 2905 (vs), 1433 (vs), 1381 (s), 1248 (s), 1167 (w), 1134
(w), 1101 (w), 1074 (w), 988 (s), 943 (w), 916 (w), 872 (s), 845
(vs), 781 (m), 760 (m), 727 (m), 700 (m), 685 (m), 627 (m), 610
(m), 517 (w), 482 (s), 438 (m). 1H NMR (benzene-d6, δ): 7.18
(m, 4H, Ar), 7.01 (m, 6H, Ar), 0.49 (s, 18H, N(Si(CH3)3)2), 0.11
(s, 36H, PhC[NSi(CH3)3]2). 13C NMR (benzene-d6, δ): 183.8
(s, PhC[NSiMe3]2), 142.2 (s, Ar), 128.4 (dt, Ar, 1J C-H ) 160 Hz,
2
2H, CH2Ph, J Y-H ) 3 Hz), 1.39 (s, 4H, THF-â-CH2), 0.18 (s,
36H, PhC[NSi(CH3)3]2). 13C NMR (benzene-d6, δ): 183.6 (s,
PhC[NSi(CH3)3]2), 155.1 (s, Ar), 143.3 (s, Ar), 128.7 (d, Ar, 1J C-H
1
1
) 158 Hz), 128.1 (d, Ar, J C-H ) 160 Hz), 126.3 (d, Ar, J C-H
) 159 Hz), 124.0 (d, Ar, J C-H ) 153 Hz), 116.7 (d, Ar, J C-H
) 157 Hz), 70.9 (t, THF-R-CH2, J C-H ) 149 Hz), 53.4 (dt,
1
1
1
1
1
CH2Ph, J C-H ) 118 Hz; J Y-C ) 31 Hz), 25.3 (t, THF-â-CH2,
2J C-H ) 7 Hz), 128.0 (d, Ar, J C-H ) 163.5 Hz), 126.5 (d, Ar,
1J C-H ) 135 Hz), 2.7 (q, PhC[NSi(CH3)3]2), J C-H ) 118 Hz).
1
1

Bis(benzamidinato)yttrium Compounds
Organometallics, Vol. 15, No. 9, 1996 2289
89Y NMR (benzene-d6, δ): 549. Anal. Calcd (found) for
3J H-H ) 9.0 Hz), 3.23 (s, OCH3), 0.29 (s, 36H, PhC[NSi(CH3)3]2).
13C NMR (benzene-d6,δ): 185.1 (s, PhC[NSiMe3]2), 159.8 (s,
C
37H61N4OSi4Y: C, 57.04 (57.05); H, 7.89 (7.97); Y, 11.41
(11.55).
P r ep a r a tion of [P h C(NSiMe3)3]2YCH(SiMe3)2 (8). Li-
1
2
Ar), 136.1 (s, Ar), 127.5 (dt, Ar, J C-H ) 160 Hz, J C-H ) 7
1
2
Hz), 113.5 (dd, Ar, J C-H ) 160 Hz, J C-H ) 10 Hz), 54.6 (q,
1
1
OCH3, J C-H ) 144 Hz), 3.2 (q, PhC[NSi(CH3)3]2, J C-H ) 118
Hz).
CH(SiMe3)2 (3.3 g, 19.8 mmol) was added to a solution of 2
(15.2 g, 20.5 mmol) in toluene (200 mL) at -80 °C. The
suspension was slowly warmed to room temperature and
stirred overnight. The reaction mixture was evaporated in
vacuo, and the residual sticky solid was dissolved in 150 mL
of pentane. After filtration, the pentane was removed, leaving
a viscous oil which slowly solidified yielding 8 (12.8 g, 16.5
mmol, 83%) as a colorless crystalline material. IR (KBr/Nujol,
cm-1): 2936 (vs), 2481 (w), 2363 (w), 2338 (w), 2101 (w), 2010
(w), 1887 (w), 1773 (w), 1601 (w), 1578 (w), 1435 (vs), 1378
(s), 1292 (w), 1248 (s), 1165 (m), 1074 (m), 1009 (s), 986 (s),
920 (m), 845 (vs), 785 (s), 760 (s), 723 (s), 702 (s), 683 (s), 664
(m), 594 (m), 486 (m), 440 (m). 1H NMR (benzene-d6, δ): 7.15
(m, 4H, Ar), 6.97 (m, 6H, Ar), 0.47 (s, 18H, CH(Si(CH3)3)2),
0.07 (s, 36H, PhC[NSi(CH3)3]2), -0.94 (d, 1H, CH(SiMe3)2,
2J Y-H ) 1.8 Hz). 13C NMR (benzene-d6, δ): 184.6 (s, PhC[NSi-
Molecu la r Or bita l Ca lcu la tion s. All molecular orbital
calculations were performed with ZINDO94, installed on a HP-
750 workstation. The theoretical Γ’s, provided by the program,
were used.44 The bond lengths and angles of the models
[HC(NH)2]2YCH3 and [C5H5]2YCH3 were taken from X-ray
crystal data, and the models were restricted to C2 and C2v
symmetry, respectively. The Y-Cσ bond distance was set at
2.48 Å. A full list of the Cartesian coordinates and Mulliken
analyses of [HC(NH)2]2YCH3 and [C5H5]2YCH3 can be found
in the Supporting Information.
X-r a y Cr yst a llogr a p h ic An a lysis of [p -MeOC6H 4C-
(NSiMe3)2]2YCH(SiMe3)2 (8OMe). A suitable colorless poly-
facial crystal was glued on top of a glass fiber in a drybox and
transferred into the cold nitrogen stream of the low-temper-
ature unit51 mounted on an Enraf-Nonius CAD-4F diffractom-
eter interfaced to a MicroVAX-2000 computer. The crystals
reflected well but showed a relatively very high background
scattering, probably caused by fluorescence of the Y atoms.
Unit cell parameters and orientation matrix were determined
from a least-squares treatment of the SET4 setting angles52
of 22 reflections in the range 14.76° < θ < 21.61°. The unit
cell was identified as monoclinic, space group P21/a. Reduced
cell calculations did not indicate any higher metric lattice
symmetry,53 and examination of the final atomic coordinates
of the structure did not yield extra metric symmetry ele-
ments.54 The intensity of three standard reference reflections,
monitored every 2 h of X-ray exposure time, showed no greater
fluctuations during data collection than those expected from
Poisson statistics, indicating crystal and electronic stability.
A 360° Ψ-scan for a reflection close to axial (422h) showed a
variation in intensity of less than 8% about the mean value.
Intensity data were corrected for Lorentz and polarization
effects and scale variation but not for absorption. Standard
deviation σ(I) in the intensities was increased according to an
analysis of the excess variance of the reference reflection:
Variance was calculated on the basis of counting statistics and
the term (P2I2), where P ()0.0078) is the instability constant55
as derived from the excess variance in the reference reflections.
Equivalent reflections were averaged and stated observed if
satisfying the I g 2.5σ(I) criterion of observability. The
structure was solved by Patterson methods, and extension of
the model was accomplished by direct methods applied to
difference structure factors using the program DIRDIF.56 The
positional and anisotropic thermal displacement parameters
for the non-hydrogen atoms refined with block-diagonal least-
squares procedures (CRYLSQ)57 minimizing the function Q )
Σh [w(|Fo| - k|Fc|)2]. A subsequent difference Fourier synthesis
resulted in the location of all the hydrogen atoms which
coordinates were included in the refinement. Final refinement
on Fo by full-matrix least-squares techniques with anisotropic
thermal displacement parameters for the non-hydrogen atoms
and isotropic thermal displacement parameters for the hydro-
gen atoms converged at RF ) 0.051 (wR ) 0.029). Weights
were introduced in the final refinement cycles. A final
difference Fourier map did not show any significant residual
1
2
Me3]2), 141.9 (s, Ar), 128.6 (dt, Ar, J C-H ) 164 Hz, J C-H ) 7
1
1
Hz), 128.2 (d, Ar, J C-H ) 163 Hz), 126.5 (d, Ar, J C-H ) 155
1
1
Hz), 43.5 (dd, CH(SiMe3)2, J C-H ) 88 Hz, J Y-C ) 30 Hz), 5.2
1
(q, CH(Si(CH3)3)2, J C-H ) 116 Hz), 2.9 (q, PhC[NSi(CH3)3]2,
1J C-H ) 119 Hz). 89Y NMR (benzene-d6, δ): 721. Anal. Calcd
(found) for C33H65N4Si6Y: C, 51.12 (51.07); H, 8.45 (8.48); Y,
11.47 (11.59).
P r ep a r a tion of [p -MeOC6H4C(NSiMe3)2]2YCH(SiMe3)2
(8OMe). Compound 8OMe was prepared by a similar procedure
as 8 starting from 2OMe (3.2 g, 4.1 mmol) and LiCH(SiMe3)2
(0.7 g, 4.2 mmol). Repeated recrystallization from pentane
yielded 8OMe (2.2 g, 2.6 mmol, 63%) as colorless crystals. IR
(KBr/Nujol, cm-1): 2940 (vs), 2874 (s), 2749 (w), 1609 (s), 1576
(w), 1512 (s), 1408 (vs, br), 1292 (s), 1248 (vs), 1171 (s), 1107
(w), 1034 (s), 988 (s), 843 (vs), 758 (vs), 741 (vs), 723 (s), 685
(m), 669 (m), 644 (s), 633 (m), 604 (w), 596 (w), 534 (w), 503
(s), 426 (m), 407 (w). 1H NMR (benzene-d6, δ): 7.11 (d, 4H,
3
3
Ar, J H-H ) 8.8 Hz), 6.62 (d, 4H, Ar, J H-H ) 8.8 Hz), 3.20 (s,
6H, OCH3), 0.50 (s, 18H, CH(Si(CH3)3)2), 0.13 (s, 36H, PhC-
[NSi(CH3)3]2), -0.91 (d, 1H, CH(SiMe3)2, 2J Y-H ) 1.3 Hz). 13C
NMR (benzene-d6, δ): 184.8 (s, p-MeO-C6H4C[NSiMe3]2), 160.0
1
2
(s, Ar), 134.6 (s, Ar), 127.9 (dd, Ar, J C-H ) 159 Hz, J C-H ) 7
1
2
Hz), 113.4 (dd, Ar, J C-H ) 160 Hz, J C-H ) 7 Hz), 54.6 (q,
1
1
OCH3, J C-H ) 144 Hz), 42.9 (dd, CH(SiMe3)2, J C-H ) 88 Hz,
1J Y-C ) 31 Hz), 5.2 (q, CH(Si(CH3)3)2, J C-H ) 118 Hz), 2.9 (q,
1
1
PhC[NSi(CH3)3]2, J C-H ) 119 Hz). Anal. Calcd (found) for
C
35H69N4O2Si6Y: C, 50.32 (50.38); H, 8.33 (8.39).
P r ep a r a tion of {[P h C(NSiMe3)2]2Y(µ-H)}2 (9). A solu-
tion of 8 (2.5 g, 3.2 mmol) in benzene (50 mL) was cooled to
-196 °C and brought under 1 atm of dihydrogen. The flask
with the frozen solution was warmed to room temperature and
stirred under H2 for 3 days. Then the solvent was evaporated
until crystallization started. Cooling to 6 °C afforded 9 (1.4
g, 1.1 mmol, 71%) as colorless crystals. IR (KBr/Nujol, cm-1):
3023 (sh), 2925 (vs), 2870 (vs), 1946 (w), 1927 (w), 1896 (w),
1879 (w), 1773 (w), 1447 (vs), 1400 (vs), 1300 (s), 1257 (s), 1246
(vs), 1170 (m), 995 (s), 918 (m), 841 (vs), 785 (s), 758 (vs), 723
(s), 700 (s), 685 (m), 660 (m), 482 (m). 1H NMR (benzene-d6,
1
δ): 8.28 (t, 1H, Y-H-Y, J Y-H ) 27.6 Hz), 7.39 (m, 4H, Ar),
7.09 (m, 6H, Ar), 0.21 (s, 36H, PhC[NSi(CH3)3]2). 13C NMR
(benzene-d6, δ): 184.9 (s, PhC[NSiMe3]2), 143.1 (s, Ar), 128.3
1
2
1
(dt, Ar, J C-H ) 164 Hz, J C-H ) 6 Hz), 126.3 (d, Ar, J C-H
)
(51) Van Bolhuis, F. J . Appl. Crystallogr. 1971, 4, 263.
(52) De Boer, J . L.; Duisenberg, A. J . M. Acta Crystallogr. 1984,
A40, C410.
(53) Spek, A. L. J . Appl. Crystallogr. 1988, 21, 578.
(54) (a) Le Page, Y. J . Appl. Crystallogr. 1987, 20, 264. (b) Le Page,
Y. J . Appl. Crystallogr. 1988, 21, 983.
1
162 Hz), 3.2 (q, PhC[NSi(CH3)3]2, J C-H ) 119 Hz). Anal.
Calcd (found) for C52H94N8Si8Y2: C, 50.62 (50.59); H, 7.68
(7.65); Y, 14.41 (14.46).
NMR-Scale P r epar ation of {[p-MeOC6H4C(NSiMe3)2]2Y-
(µ-H)}2 (9OMe). An NMR tube equiped with a Teflon needle
valve was charged with 8OMe (34 mg, 0.04 mmol) in benzene-
d6 (0.7 mL). After the solution had been cooled to -196 °C
and evacuated, dihydrogen was added (1 atm) and subse-
quently the solution warmed at 50 °C for 12 h. 1H NMR
(55) McCandlish, L. E.; Stout, G. H.; Andrews, L. C. Acta Crystallogr.
1975, A31, 245.
(56) Beurskens, P. T.; Admiraal, G.; Beurskens, G.; Bosman, W. P.;
Garc´ıa-Granda, S.; Gould, R. O.; Smits, J . M. M.; Smykalla, C. The
DIRDIF program system, Technical Report of the Crystallography
Laboratory; University of Nijmegen: Nijmegen, The Netherlands, 1992.
(57) Olthof-Hazekamp, R. QRYLSQ, Xtal3.0 Reference Manual; Hall,
S. R., Stewart, J . M., Eds.; University of Western Australia and
Maryland; Lamb: Perth, Australia, 1992.
spectroscopy showed that all 8OMe had been converted into
1
9OMe
.
1H NMR (benzene-d6, δ): 8.31 (t, 1H, Y-H-Y, J Y-H
)
3
27.8 Hz), 7.35 (d, 4H, Ar, J H-H ) 8.6 Hz), 6.76 (d, 6H, Ar,

2290 Organometallics, Vol. 15, No. 9, 1996
Duchateau et al.
Ta ble 5. Deta ils of th e X-r a y Str u ctu r e Deter m in a tion of [p-MeOC6H4C(NSiMe3)2]2YCH(SiMe3)2 (8OMe) a n d
{P h C(NSiMe3)2]2Y(µ-H)}2 (9)
8OMe
9
formula
Mn
C35H69N4O2Si6Y
835.38
(C26H47N4Si4Y)2
1233.86
cryst system
space group
a, Å
b, Å
c, Å
monoclinic
P21/a
22.637(2)
18.032(1)
12.020(1)
triclinic
P1h
13.526(1)
14.052(1)
20.027(2)
R, deg
â, deg
γ, deg
V, Å3
D
Z
104.385(8)
108.934(7)
93.455(8)
3446.2(5)
1.189
2
101.833(8)
4802.2(7)
1.155
4
calc, g‚mol-3
F(000)
1784
13.98
1304
18.6
µ(Mo KR), cm-1
cryst size, mm
T, K
0.20 × 0.25 × 0.33
0.37 × 0.45 × 0.50
130
130
θ range, deg: min, max
1.13, 27.0
0.71073
graphite
∆ω ) 0.85 + 0.34 tan θ
h, -28f28; k, 0f23; l, 0f15
11 326
10 461
5673
0.049
0.070
1028
1.12, 25.6
0.71073
graphite
∆ω ) 0.75 + 0.34 tan θ
h, 0f16; k, -17f17; l, -24f22
13 522
12 931
8746
0.031
0.049
1182
λ (Mo KR), Å
monochromator
ω/2θ scan, deg
data set
tot. data
unique data
obsd data (I g 2.5σ(I))
R1 ()Σ(I - hI)/ΣI)
R2 ()Σσ/ΣI)
no. of equiv reflcns
no. of refined params
final agreement factors
RF ) Σ(||Fo| - |Fc||)/Σ|Fo|
709
990
0.051
0.043
wR ) [Σ(w(|Fo| - |Fc|)2)/Σw|Fo| ]1/2
0.029
0.037
2
weighting scheme
1/σ2(F)
1.841
1/σ2(F)
1.761
S ) [Σw(|Fo| - |Fc|)2/(m - n)]1/2 a
resid electron density in final diff Fourier map, e/Å3
max shift/σ in final cycle
-0.79, 0.65
0.3988
0.021 10
-0.60, 0.70
0.2504
0.0122
av shift/σ in final cycle
a
m ) no. of observations and n ) no. of variables.
features. Crystal data and experimental details of the struc-
ture determination are compiled in Table 5. Scattering factors
were taken from Cromer and Mann.58 Anomalous dispersion
factors taken from Cromer and Liberman.59 All calculations
were carried out on the HP9000/735 computer at the Univer-
sity of Groningen with the program packages Xtal,60 PLA-
TON61 (calculation of geometric data), and ORTEP62 (prepa-
ration of illustrations).
X-r a y Cr ysta llogr a p h ic An a lysis of {[P h C(NSiMe3)2]2Y-
(µ-H)}2 (9). The general procedure for solving the structure
was as outlined above. Precise lattice parameters and their
standard deviation were derived from the angular settings of
22 reflections in the range 11.81° < σ < 16.88°. The triclinic
unit cell (space group P1h) was checked for higher symmetry.53,54
A correction for absorption was judged not to be necessary in
view of the observed small intensity variation (9%) for a 360°
Ψ-scan of the close to axial reflection (204h). The structure was
solved by Patterson methods and extension of the model was
accomplished by direct methods, applied to difference structure
factors using the program DIRDIF.56 The positional and
anisotropic thermal displacement parameters for the non-
hydrogen atoms refined with block-diagonal least-squares
procedures (CRYLSQ)57 minimizing the function Q ) Σh [w(|Fo|
- k|Fc|)2]. A subsequent difference Fourier synthesis resulted
in the location of all the hydrogen atoms. Following the
inclusion of the positional parameters of hydrogen atoms, the
remainder of the structure refined smoothly. High thermal
displacement motion was sited for the C(44) and C(46) atoms,
suggesting some degree of disorder, but no resolvable disorder
could be stated. The methyl hydrogen atoms bonded to the
C(44) and C(45) atoms did not refine well and were ultimately
included in the final refinement riding on their carrier atoms
with their positions calculated by using sp3 hybridization at
the C atom as appropriate with a fixed C-H distance of 0.96
Å. Final refinement on Fo by full-matrix least-squares tech-
niques with anisotropic thermal displacement parameters for
the non-hydrogen atoms and isotropic thermal displacement
parameters for the hydrogen atoms converged at RF ) 0.043
(wR ) 0.037). Weights were introduced in the final refinement
cycles. A final difference Fourier map did not show unusual
residual peaks. The crystal exhibited some secondary extinc-
tion for which the Fc values were corrected by refinement of
an empirical isotropic extinction parameter.63 Crystal data
and experimental details of the structure determination are
compiled in Table 5.
Ack n ow led gm en t. This work was financially sup-
ported by Shell Research B.V. Amsterdam, which is
gratefully acknowledged. The 89Y NMR spectra were
recorded by J . H. G. Frijns (Shell Research B.V. Am-
sterdam), who is gratefully acknowledged.
Su p p or tin g In for m a tion Ava ila ble: Listing of the Car-
tesian coordinates and Mulliken population analyses of [C5H5]2-
YCH3 and [HC(NH)2]2YCH3 and all atomic coordinates, ther-
mal parameters, bond distances, bond angles, and torsion
angles for 8OMe and 9 (35 pages). Ordering information is
given on any current masthead page.
(58) Cromer, D. T.; Mann, J . B. Acta Crystallogr. 1968, A24, 321.
(59) Cromer, D. T.; Liberman, D. J . Chem. Phys. 1970, 53, 1891.
(60) Hall, S. R.; Flack, H. D.; Stewart, J . M. Xtal3.2 Reference
Manual; Universities of Western Australia and Maryland; Lamb:
Perth, Australia, 1992.
(61) Spek, A. L. Acta Crystallogr. 1990, A46, C34.
(62) J ohnson, C. K. ORTEP; Report ORNL-3794; Oak Ridge Na-
tional Laboratory: Oak Ridge, TN, 1965.
OM950813+
(63) Zachariasen, W. H. Acta Crystallogr. 1967, 23, 558.