5(N-methylbenzoylamino)-2,2,6,6-tetramethylheptan-3-ol as a new class of recoverable chiral auxiliary

DOI: 10.1016/0040-4039(96)00137-2

Source and publish data:

Tetrahedron Letters p. 1863 - 1866 (1996)

Update date:2022-08-04

Topics:

Authors:

Yamamoto, Yoshinori

Kin, Hirofumi

Suzuki, Ichiro

Asao, Naoki

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Article abstract of DOI:10.1016/0040-4039(96)00137-2

Reduction of α-ketoesters bearing 5(N-methylbenzoylamino)-2,2,6,6-tetramethylheptan-3-ol as a chiral auxillary proceeds with high diastereoselectivity by using DIBAL as a reducing agent. The chiral auxiliary is recovered upon treatment with base, and α-hy

Full text of DOI:10.1016/0040-4039(96)00137-2

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