Journal of the Chemical Society, Dalton Transactions p. 1203 - 1207 (1996)
Update date:2022-08-03
Topics:
Menon, Saija C.
Singh, Harkesh B.
Patel, Rajan P.
Kulshreshtha, Shailendra K.
The condensation of bis(2-formylphenyl) telluride 1 with ethane-1,2-diamine yielded the novel macrocyclic tellurium ligand 2 via metal-free dimerisation. Crystals of 2 are triclinic, space group P1 with a = 7.956(3), b = 9.885(2), c = 10.068(2) A, Z = 1. Hydrogenation of macrocycle 2 provided the corresponding saturated tetraazamacrocycle 3, protonation of which with HBr afforded 4. The co-ordination chemistry of 2 has been studied with 'soft' metal ions such as palladium(II) and mercury(II). N,N′-Bis[(2-chlorotelluranyl)benzylidene]ethane-1,2-diamine has also been characterised by an X-ray diffraction study, with triclinic space- group P1, a = 7.71(1), b = 7.90(1), c = 8.52(1) A and Z = 1.
Shanghai PotentPharm Science and Technology Co.,Ltd
Contact:86-021-51969655
Address:Unit B, Building 18, No.300, Chuantu Rd,Pudong District, Shanghai 201202, China
Beijing Mashi Fine Chemical Co.,Ltd.
Contact:+86-10-61271592
Address:Room 506, Section B, Kaichi Mansion, Industrial Development
Zhejiang Golden-Shell Pharmaceutical Co.,Ltd.
Contact:+86-576-87501888 / 87501988
Address:No.89 Zhongxing Road. Li'ao, Yuhuan, Zhejiang, China
LianYunGang Chiral Chemical(CHINA) CO.,LTD
Contact:+86-518-83616958 +86-519-82884848
Address:LianYunGang Chemical Industry Park (JiangSu)
Yantai Derun Liquid Crystal Materials Co. Ltd.
website:http://www.ytderun.com
Contact:86-535-6300169
Address:ROOM 90, XIANGFU STREET, FUSHAN NEW-HIGH-TECH IDUSTRY ZONE, YANTAI
Doi:10.1021/jo9520194
(1996)Doi:10.1016/0960-894X(96)00153-9
(1996)Doi:10.1016/S0968-0896(98)00205-3
(1999)Doi:10.1016/S0040-4039(01)00612-8
(2001)Doi:10.1039/P19960000931
(1996)Doi:10.1002/(SICI)1097-458X(199605)34:5<351::AID-OMR882>3.0.CO;2-H
(1996)
