Total synthesis of calyculin A-Construction of the C(9)-C(37) fragment

DOI: 10.1039/CC9960000871

Source and publish data:

Chemical Communications p. 871 - 872 (1996)

Update date:2022-07-29

Topics:

Authors:

Yokokawa, Fumiaki

Hamada, Yasumasa

Shioiri, Takayuki

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Article abstract of DOI:10.1039/CC9960000871

The potent protein phosphatase inhibitor calyculin A is formally synthesized via construction of the C(9)-C(37) fragment 2 by a Wittig reaction of the C(9)-C(25) spiroketal fragment with the C(26)-C(37) phosphonium salt.

Full text of DOI:10.1039/CC9960000871

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