Tris(triorganostannyltetrazoles): Synthesis and supramolecular structures

DOI: 10.1039/dt9960001857

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1857 - 1865 (1996)

Update date:2022-07-29

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Authors:

Hill, Michael

Mahon, Mary F.

Molloy, Kieran C.

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Article abstract of DOI:10.1039/dt9960001857

Six trifunctional triorganotin tetrazoles, (R₃SnN₄CCH₂CH₂)₃C(NO ₂) and 1,3,5-(R₃SnN₄C)₃C₆H₃(R = Me, Et or Bu), have been synthesised by a cycloaddition route from SnR₃(N₃) and either (NCCH₂CH₂)₃C(NO₂) or 1,3,5-(NC)₃C₆H₃ as dipblarophile. The compounds have been characterised by ¹H, ¹³C, ¹¹⁹Sn NMR and ¹¹⁹Moessbauer spectroscopies, while the crystal structures of the tributyltin examples of each series reveal they adopt layered supramolecular arrays.

Full text of DOI:10.1039/dt9960001857

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