
Chemical Communications p. 1041 - 1042 (1996)
Update date:2022-08-06
Topics:
Shiu, Lin-Hung
Shu, Hsin-Kuo
Cheng, Da-Hsin
Wang, Sue-Lein
Liu, Rai-Shung
Treatment of tungsten-η1-7-oxabicyclo[2.2.1]heptadiene and -η1-7-oxabicyclo[2.2.1]heptene with CF3SO3H leads to atypical carbon-carbon bond scission and deoxygenation; the reaction intermediates in the bond scission involves a tungsten-η1-2-hydrofurylium cation.
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