Tetrahedron Letters p. 3915 - 3918 (1996)
Update date:2022-08-04
Topics:
Fishwick, Colin W.G.
Foster, Richard J.
Carr, Robin E.
The γ-lactam based alkaloid cynometrine has been synthesised in four steps from 1-methyl-imidazole-4-carboxaldehyde. The key step involves an efficient regio-, stereo-, and chemoselective 1,3-dipolar cycloaddition of a dithiolane-fused azomethine ylide.
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