Chemical and Pharmaceutical Bulletin p. 927 - 932 (1996)
Update date:2022-08-02
Topics: Final steps Deacetylation Ozonolysis Protection of Amino Group
Shinozaki, Katsuo
Mizuno, Kazuhiro
Masaki, Yukio
D-erythro-Sphingosine (1) was synthesized from D-glucosamine (2) as a chiral pool through stereoinversion of the C(3)-hydroxyl group via an oxidation-reduction sequence, transformation to the erythro-amino-alcohol chiron (9) protected as the oxazolidinone, and elongation of the side chain at the C(6)-position of the derived chloride (12).
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Doi:10.1002/rcm.8576
(2020)Doi:10.1021/jo960818w
(1996)Doi:10.1016/S0040-4020(00)00660-8
(2000)Doi:10.1016/S0040-4020(97)00048-3
(1997)Doi:10.1039/CC9960001243
(1996)Doi:10.1021/jo9606766
(1996)
