Chemical Communications p. 1375 - 1376 (1996)
Update date:2022-09-26
Topics:
Horton, Andrew D.
De With, Jan
Reaction of {(Me3Si)2N}2Zr(CH2Ph)2 1 with B(C6F5)3 gives a cationic benzyl complex, which at -25°C, expels toluene to afford {(Me3Si)2N}Zr(CH2SiMe2NSiMe 3){ηn-PhCH2-B(C6F 5)3} 2; strong anion coordination to zirconium in cyclometallation product 2 suppresses alkene polymerization, whereas the analogous cationic NMe2Ph adduct 3, formed by protonolysis of 1, polymerizes both ethene and propene.
Jiangsu King Road New Materials Co., Ltd.
website:http://www.jskingroad.com
Contact:0519-85720726 0519-85720721 15006126856
Address:No.1,Weihua Road,Xinbei District,Changzhou City,Jiangsu Province
Shanghai Mio Chemical Co., Ltd
Contact:0086 21- 64401188-622
Address:16 Floor NO.2 Jiefang Building, No. 4855 Dushi Road, 201100 Shanghai, P.R.China
Contact:+86-575-82733999 0575-82732999
Address:hangzhou gulf fine chemical zone,shangyu city,zhejiang province
Contact:86 311 85902108 / 85902109
Address:room 1001-1005 ,huanghe Road ,shijiazhuang ,China
Nantong LiKai Chemical Co.,Ltd
Contact:+86-513-89068669
Address:Jincheng Science Park
Doi:10.1002/anie.202111163
(2021)Doi:10.3987/COM-92-S14
(1993)Doi:10.1002/hlca.19940770604
(1994)Doi:10.1021/ja00066a056
(1993)Doi:10.1134/S0036024406030046
(2006)Doi:10.1039/DT9930001281
(1993)
