Organometallics p. 1410 - 1413 (1987)
Update date:2022-08-03
Topics:
Iovel, Irina G.
Goldberg, Yuri Sh.
Shymanska, Mariya V.
Lukevics, Edmunds
A number of quaternary ammonium, phosphonium, and arsonium hexachloroplatinates have been synthesized and used as hydrosilylation catalysts. The highest activity was observed for the quaternary hexachloroplatinates with highly lipophilic cations. Phase-transfer agents (onium salt, crown ether) were found to activate K2PtCl6 during hydrosilylation by solubilizing the PtCl62- ion. It has been shown that polymer-bound quaternary phosphonium hexachloroplatinate is also an effective hydrosilylation catalyst that can be used repeatedly without appreciable loss of activity.
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(2019)
