Tetrahedron Letters p. 8441 - 8444 (1994)
Update date:2022-09-26
Topics:
Van Der Deen, Hanneke
Hof, Robert P.
Van Oeveren, Arjan
Feringa, Ben L.
Kellogg, Richard M.
Several lipases catalyse the transesterification of γ-acyloxyfuranones in organic solvents with high enantioselectivities. This method has been used for the kinetic resolution of 5-acetoxy-2(5H)-furanone, 5-acetoxy-4-methyl-2(5H)-furanone and 5-propionyloxy-2(5H)-furanone, in e.e.'s ranging from 68-98%.
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