Inorganic Chemistry p. 1444 - 1447 (1964)
Update date:2022-08-04
Topics:
Papetti, Stelvio
Schaeffer
Troscianiec
Heying
When the carbons of carborane participate in exocyclic rings the thermal rearrangement of the ortho carborane nucleus to the meta configuration is opposed. These molecules as a whole therefore resist degradation at elevated temperature. Chemically these cyclics are stable under acid conditions but the silicon-carborane carbon bond is attacked by bases. Additional types of cyclic silazanes are reported and reactions of some functional groups at the silicon atoms are described.
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