Vicarious nucleophilic substitution of hydrogen in nitrophenyl toluenesulfonates

DOI: 10.1016/S0040-4020(97)00143-9

Source and publish data:

Tetrahedron p. 4739 - 4750 (1997)

Update date:2022-08-04

Topics:

Authors:

Makosza, Mieczyslaw

Ziobrowski, Tadeusz

Serebriakov, Mikhail

Kwast, Andrzej

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Article abstract of DOI:10.1016/S0040-4020(97)00143-9

Toluenesulfonates of nitrophenols react with carbanions possessing leaving groups giving products of the vicarious nucleophilic substitution of hydrogen. The yields and orientation depend on the reaction conditions and the structure of the reagents. The products obtained can be easily hydrolyxed to the corresponding phenols or - in certain cases - to hydroxynitrobenzaldehydes.

Full text of DOI:10.1016/S0040-4020(97)00143-9

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