
Acta Crystallographica, Section C: Crystal Structure Communications p. 1961 - 1963 (1996)
Update date:2022-08-03
Topics:
Ross, Jennifer-Nicola
Wardell, James L.
Low, John N.
Ferguson, George
The title compound, μ-{N,N′-bis[trans-5-(methoxymethyl)-2-phenyl-1,3-dioxan-5-yl] ethanediamide(2-)}-bis(triphenyltin), [Sn2(C6H5)6(C26H 30N2O8)], was isolated from the products of the (triphenylstannyl)-methylation of a 1:1 mixture of stereoisomers of N,N′-bis(5-hydroxymethyl-2-phenyl-1,3-dioxan-5-yl)ethanediamide. The molecule lies about an inversion centre and the unique Sn atom has distorted tetrahedral geometry, with Sn-Calkyl and Sn-Caryl distances of 2.154(2) and 2.138(2)-2.147 (3) A, respectively, and C-Sn-C angles in the range 105.5 (1)-113.2(1)°.
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