Chemistry Letters p. 671 - 672 (1996)
Update date:2022-08-03
Topics:
Honda, Kiyoshi
Yoshii, Ichiro
Inoue, Seiichi
Highly stereoselective elongation of a functionalized E isoprene unit on the Z terminal methyl of prenol was achieved by the N-ylide rearrangement of N-tiglyl-β-methallyldimethyl-ammonium salt. (E,Z)-Rearrangement product was converted into 13-cis-retinol via useful conjugated triene isoprenoid synthon.
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