A new strategy for the conversion of aldehydes into difluoromethyl ketones

DOI: 10.1016/0040-4039(96)00947-1

Source and publish data:

Tetrahedron Letters p. 4711 - 4712 (1996)

Update date:2022-08-04

Topics:

Authors:

Piettre, Serge R.

Girol, Catherine

Schelcher, Charles G.

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Article abstract of DOI:10.1016/0040-4039(96)00947-1

A three-step sequence of reactions involving the lithium salt of diethyl difluoromethylphosphonate as a difluoromethyl carrier is shown to efficiently convert aliphatic and arylic aldehydes 2 into difluoromethyl ketones 1 via a unusual carbon-phosphorus bond scission.

Full text of DOI:10.1016/0040-4039(96)00947-1

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