A DAST-free route to aryl(difluoromethyl)phosphonic esters

DOI: 10.1039/cc9960001615

Source and publish data:

Chemical Communications p. 1615 - 1616 (1996)

Update date:2022-08-05

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Authors:

Blades Blades

Cockerill

Easterfield

Lequeux Lequeux

Percy Percy

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Article abstract of DOI:10.1039/cc9960001615

The cerium(III)-mediated addition of diethyl (lithiodifluoromethyl)phosphonate to a benzoquinone monoketal allows the synthesis of phenol bearing the (diethoxyphosphonyl)difluoromethyl group via short, scaleable reaction sequences which avoid the use of t

Full text of DOI:10.1039/cc9960001615

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