
Chemical Communications p. 1907 - 1908 (1996)
Update date:2022-08-03
Topics:
Riches, Bruce H.
Kitching, William
cis-5-Mesyloxycyclooctyltrimethylstannane solvolyses in 80% ethanol-20% water ca. 800 times faster than the trans-isomer and affords exclusively bicyclo[3.3.0]octane, consistent with a stereoelectronically regulated 1,5-percaudal interaction (ε-effect) from the C-Sn σ-bond.
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