Total synthesis of preswinholide A. 1. Stereoselective synthesis of the C11-C23 segment

DOI: 10.1016/0040-4039(96)01503-1

Source and publish data:

Tetrahedron Letters p. 6881 - 6884 (1996)

Update date:2022-07-29

Topics:

Authors:

Nagasawa, Kazuo

Shimizu, Isao

Nakata, Tadashi

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Article abstract of DOI:10.1016/0040-4039(96)01503-1

The C11-C23 segment of preswinholide A was stereoselectively synthesized based on the iterative construction of 1,3-polyol chains using a series of sequential reactions which involves the Sharpless asymmetric epoxidation of allyl alcohol and Pd-catalyzed hydrogenolysis of alkenyl oxirane with HCOOH as the key reactions.

Full text of DOI:10.1016/0040-4039(96)01503-1

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