Tetrahedron Letters p. 7107 - 7110 (1996)
Update date:2022-08-05
Topics:
Miyaoka, Hiroaki
Saka, Yasuhiro
Miura, Shotaro
Yamada, Yasuji
The first total synthesis of PAF antagonist marine diterpenoid phomactin D was achieved from L-ascorbic acid. This synthesis involves the formation of bicyclo[2.2.2]octane derivative 3 by the sequential Michael reaction, oxidative cleavage of the double bond of 4 and cyclization of sulfone 18.
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