The reactions of gallium metal with (p-MeOC6H4)3AsI2 and Et3AsI2; isolation of a novel gallium(II) arsine complex with a gallium-gallium bond and the X-ray crystal structures of GaI3[(p-MeOC6H4)3As] and Ga2I4(AsEt3)2

DOI: 10.1039/CC9960002179

Source and publish data:

Chemical Communications p. 2179 - 2180 (1996)

Update date:2022-08-02

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Authors:

Beagley, Brian

Godfrey, Stephen M.

Kelly, Katharine J.

Kungwankunakorn, Sukjit

McAuliffe, Charles A.

Pritchard, Robin G.

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Article abstract of DOI:10.1039/CC9960002179

The reactions of (P-MeOC₆H₄)₃AsI₂ and Et₃AsI₂ with gallium metal powder produce the metal complexes GaI₃[(p-MeOC₆H₄)₃As] and Ga₂I₄(AsEt₃)₂, respectively; the latter represents a unique example of a gallium-tertiary arsine complex containing a gallium-gallium bond, and both structures illustrate the subtle effect of the organic substituent on the arsenic atoms.

Full text of DOI:10.1039/CC9960002179

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