Chemical and Pharmaceutical Bulletin p. 1823 - 1830 (1996)
Update date:2022-08-02
Topics:
Shinozaki, Katsuo
Mizuno, Kazuhiro
Wakamatsu, Hideaki
Masaki, Yukio
Manipulation of cis (4S,5S)-4,5-disubstituted 2-oxazolidinones (4, 5), derived easily from D-glucosamine (1) as a chiral pool, including degradation of the C6-carbon and/or one-carbon homologation at the C1-position allowed chiral syntheses of (2S,3S)-dihydroxy-(4S)-amino acid moieties (6-8), which are important structural components of a gastroprotective substance, AI-77- B, and a group of antitumor substances, calyculins.
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