One-electron oxidation of enol phosphates, enol phosphites and enol phosphinates. Evidence for an unprecedented P-O bond cleavage in phosphoenol radical cations in solution

DOI: 10.1039/CC9960002349

Source and publish data:

Chemical Communications p. 2349 - 2350 (1996)

Update date:2022-08-03

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Authors:

Schmittel, Michael

Steffen, Jens-Peter

Burghart, Armin

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Article abstract of DOI:10.1039/CC9960002349

For the first time phosphoenol radical cations are generated in solution and monitored by cyclic voltammetry and EPR; the sterically congested radical cations undergo an unprecedented P-O bond cleavage, the kinetics of which are determined.

Full text of DOI:10.1039/CC9960002349

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