Tetrahedron Letters p. 8057 - 8058 (1996)
Update date:2022-08-03
Topics:
O'Brien, Peter
Poumellec, Pierre
Highly enantiomerically enriched allylic alcohols have been generated by rearranging single diastereomers of meso-cyclohexene oxides using a homochiral lithium amide base. PDC oxidation of each allylic alcohol product affords a different enantiomer of a synthetically useful cyclohexenone.
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