The unusual Baeyer-Villiger rearrangement of β-lactam aldehdyes: Totally stereoselective entry to cis-3-substituted 4-formyloxy-2-azetidinones

DOI: 10.1016/0040-4039(95)00492-U

Source and publish data:

Tetrahedron Letters p. 3401 - 3404 (1995)

Update date:2022-08-02

Topics:

Authors:

Alcaide Alcaide

Aly Aly

Sierra Sierra

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)00492-U

Baeyer-Villiger oxidation of 4-formyl-β-lactams 1 with m-chloroperbenzoic acid in dichloromethane at room temperature is shown to be a convenient method for the preparation of 4-formyloxy-β-lactams 2. Some reactions of novel compounds 2 are also described

Full text of DOI:10.1016/0040-4039(95)00492-U

Products guided by the article

Product name:2-Azetidinone, 4-(formyloxy)-1-(4-methoxyphenyl)-3,3-dimethyl-

Cas No:184423-79-8

R&D Labs maybe for 184423-79-8

Shandong Yaroma Perfumery Co., Ltd.

Contact:+86- 531- 88024598

Address:7-702 Caizhi Central, 59 Gong Ye South Road, Jinan City,250101, P. R. China
Disynthesis Chemical Technology Co. Ltd.

Contact:+86-571-88194596

Address:Dengyun road 380, Gongshu district, Hangzhou city, China
Kunming Biohome Technology Co. Ltd.

website:http://www.biohometech.com/

Contact:86-871-67428869

Address:kunming
Wuxi Innopal International Trade CO.,LTD

Contact:+86-510-80711901-8003

Address:Room 402,Building 5,Longze Garden,No.17,South huanjiu Road,Yixing City, Jiangsu,China
Shanghai Haoyuan Chemexpress Co., Ltd.

website:https://www.chemexpress.com/

Contact:86-21-58950125

Address:No.3 Building, No.1999, Zhangheng Road, ZhangjiangHighTech Park, Shanghai, P.R.China,201203

Relevant to this article

Synthesis, reactivity, and computational studies of [η⁵- C₅H₅-(η⁵-C₅H₄CMe ₂C₆H₄Me)TiMe]⁺: Aromatic C-H bond activation at -50 °C

Doi:10.1021/om8000394
(2008)
Preparation of nanostructures by orthogonal self-assembly of hydrogelators and surfactants

Doi:10.1002/anie.200704609
(2008)
Asymmetric aldol reactions. A new camphor-derived chiral auxiliary giving highly stereoselective aldol reactions of both lithium and titanium(IV) enolates

Doi:10.1021/ja00004a034
(1991)
General Syntheses of 6- and 7-Carbomethoxy-trans-1-heteradecalins and 6- and 7-Carbomethoxy-trans-2-heteradecalins

Doi:10.1021/jo00362a012
(1986)
Microwave-accelerated Conjugate Addition of 2-Arylindoles to Substituted β-Nitrostyrenes in the Presence of Ammonium Trifluoroacetate: An Efficient Approach for the Synthesis of a Novel Class of CB1 Cannabinoid Receptor Allosteric Modulators

Doi:10.1002/jhet.2861
(2017)
Nucleophilic reactivities of ketene acetals

Doi:10.1002/ejoc.200400134
(2004)

Article Doi